1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols

Tomoya Miura; Shunsuke Moritani; Yota Shiratori; Masahiro Murakami

doi:10.1039/d1cc06349a

1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols

Tomoya Miura, Shunsuke Moritani, Yota Shiratori, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A unique method for the synthesis of substituted 1-naphthols by a rhodium(ii)-catalysed ring-expansion reaction of 2-triazolyl-1-indanone derivatives is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety. This journal is

Original language	English
Pages (from-to)	2710-2713
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	16
DOIs	https://doi.org/10.1039/d1cc06349a
Publication status	Published - Feb 25 2022

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A unique method for the synthesis of substituted 1-naphthols by a rhodium(ii)-catalysed ring-expansion reaction of 2-triazolyl-1-indanone derivatives is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety. This journal is ",

author = "Tomoya Miura and Shunsuke Moritani and Yota Shiratori and Masahiro Murakami",

note = "Funding Information: This work was supported in part by MEXT [Grants-in-Aid for Scientific Research (B) (20H02739) (T. M.)]. We thank Dr T. Fujihara (Kyoto University) for his kind help in X-ray analysis. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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AU - Moritani, Shunsuke

AU - Shiratori, Yota

AU - Murakami, Masahiro

N1 - Funding Information: This work was supported in part by MEXT [Grants-in-Aid for Scientific Research (B) (20H02739) (T. M.)]. We thank Dr T. Fujihara (Kyoto University) for his kind help in X-ray analysis. Publisher Copyright: © The Royal Society of Chemistry.

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N2 - A unique method for the synthesis of substituted 1-naphthols by a rhodium(ii)-catalysed ring-expansion reaction of 2-triazolyl-1-indanone derivatives is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety. This journal is

AB - A unique method for the synthesis of substituted 1-naphthols by a rhodium(ii)-catalysed ring-expansion reaction of 2-triazolyl-1-indanone derivatives is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety. This journal is

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1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols

Abstract

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