A bifunctional catalyst for carbon dioxide fixation: Cooperative double activation of epoxides for the synthesis of cyclic carbonates

Tadashi Ema; Yuki Miyazaki; Shohei Koyama; Yuya Yano; Takashi Sakai

doi:10.1039/c2cc30591g

A bifunctional catalyst for carbon dioxide fixation: Cooperative double activation of epoxides for the synthesis of cyclic carbonates

Tadashi Ema, Yuki Miyazaki, Shohei Koyama, Yuya Yano, Takashi Sakai

School of Engineering

Research output: Contribution to journal › Article › peer-review

259 Citations (Scopus)

Abstract

We have developed a very active bifunctional porphyrin catalyst showing a high turnover number (TON = 103 000) for the synthesis of cyclic carbonates from CO₂ and epoxides under solvent-free conditions.

Original language	English
Pages (from-to)	4489-4491
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	37
DOIs	https://doi.org/10.1039/c2cc30591g
Publication status	Published - Apr 9 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "We have developed a very active bifunctional porphyrin catalyst showing a high turnover number (TON = 103 000) for the synthesis of cyclic carbonates from CO2 and epoxides under solvent-free conditions.",

author = "Tadashi Ema and Yuki Miyazaki and Shohei Koyama and Yuya Yano and Takashi Sakai",

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T2 - Cooperative double activation of epoxides for the synthesis of cyclic carbonates

AU - Ema, Tadashi

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AU - Yano, Yuya

AU - Sakai, Takashi

PY - 2012/4/9

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A bifunctional catalyst for carbon dioxide fixation: Cooperative double activation of epoxides for the synthesis of cyclic carbonates

Abstract

ASJC Scopus subject areas

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