A coarse-grain model for entangled polyethylene melts and polyethylene crystallization

Kyle Wm Hall, Timothy W. Sirk, Michael L. Klein, Wataru Shinoda

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

The Shinoda-DeVane-Klein (SDK) model is herein demonstrated to be a viable coarse-grain model for performing molecular simulations of polyethylene (PE), affording new opportunities to advance molecular-level, scientific understanding of PE materials and processes. Both structural and dynamical properties of entangled PE melts are captured by the SDK model, which also recovers important aspects of PE crystallization phenomenology. Importantly, the SDK model can be used to represent a variety of materials beyond PE and has a simple functional form, making it unique among coarse-grain PE models. This study expands the suite of tools for studying PE in silico and paves the way for future work probing PE and PE-based composites at the molecular level.

Original languageEnglish
Article number244901
JournalJournal of Chemical Physics
Volume150
Issue number24
DOIs
Publication statusPublished - Jun 28 2019
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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