A new transformation of silanols. Palladium-catalyzed cross-coupling with organic halides in the presence of silver(I) oxide

Kazunori Hirabayashi; Jun Kawashima; Yasushi Nishihara; Atsunori Mori; Tamejiro Hiyama

doi:10.1021/ol990614c

A new transformation of silanols. Palladium-catalyzed cross-coupling with organic halides in the presence of silver(I) oxide

Kazunori Hirabayashi, Jun Kawashima, Yasushi Nishihara, Atsunori Mori, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

173 Citations (Scopus)

Abstract

(equation presented) The reactions of aryl-and alkenylsilanols with organic halides are found to proceed in a catalyst system of 5 mol % of Pd(PPh₃)4 and Ag₂O (1 equiv) to give the corresponding coupling products in up to 84% yield. † Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan.

Original language	English
Pages (from-to)	299-301
Number of pages	3
Journal	Organic Letters
Volume	1
Issue number	2
DOIs	https://doi.org/10.1021/ol990614c
Publication status	Published - Jul 29 1999
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol990614c

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abstract = "(equation presented) The reactions of aryl-and alkenylsilanols with organic halides are found to proceed in a catalyst system of 5 mol % of Pd(PPh3)4 and Ag2O (1 equiv) to give the corresponding coupling products in up to 84% yield. † Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan.",

author = "Kazunori Hirabayashi and Jun Kawashima and Yasushi Nishihara and Atsunori Mori and Tamejiro Hiyama",

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T1 - A new transformation of silanols. Palladium-catalyzed cross-coupling with organic halides in the presence of silver(I) oxide

AU - Hirabayashi, Kazunori

AU - Kawashima, Jun

AU - Nishihara, Yasushi

AU - Mori, Atsunori

AU - Hiyama, Tamejiro

PY - 1999/7/29

Y1 - 1999/7/29

N2 - (equation presented) The reactions of aryl-and alkenylsilanols with organic halides are found to proceed in a catalyst system of 5 mol % of Pd(PPh3)4 and Ag2O (1 equiv) to give the corresponding coupling products in up to 84% yield. † Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan.

AB - (equation presented) The reactions of aryl-and alkenylsilanols with organic halides are found to proceed in a catalyst system of 5 mol % of Pd(PPh3)4 and Ag2O (1 equiv) to give the corresponding coupling products in up to 84% yield. † Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Kyoto 606-8501, Japan.

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A new transformation of silanols. Palladium-catalyzed cross-coupling with organic halides in the presence of silver(I) oxide

Abstract

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