TY - JOUR
T1 - A relationship between chemiluminescence and reactivity of Wittig type reactions of phosphonate carbanions
AU - Motoyoshiya, Jiro
AU - Tsuboi, Shuji
AU - Kokin, Keisuke
AU - Takaguchi, Yutaka
AU - Hayashi, Sadao
AU - Aoyama, Hiromu
PY - 1998/1/1
Y1 - 1998/1/1
N2 - The chemiluminescence (CL) quantum yields (ΦCL) of oxygenation of 10-methyl-9,10-dihydroacridine-9-phosphonate carbanions depended on the phosphorus substituents. The acridinephosphonate with electron negative phosphorus substituents such as bis(2,2,2-trifluoroethyl)phosphono group showed higher ΦCL, which was considered comparing the reactivity of the phosphonoacetates in the Horner-Wadsworth-Emmons (HWE) reactions involving the corresponding phosphorus substituents.
AB - The chemiluminescence (CL) quantum yields (ΦCL) of oxygenation of 10-methyl-9,10-dihydroacridine-9-phosphonate carbanions depended on the phosphorus substituents. The acridinephosphonate with electron negative phosphorus substituents such as bis(2,2,2-trifluoroethyl)phosphono group showed higher ΦCL, which was considered comparing the reactivity of the phosphonoacetates in the Horner-Wadsworth-Emmons (HWE) reactions involving the corresponding phosphorus substituents.
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U2 - 10.1515/HC.1998.4.1.25
DO - 10.1515/HC.1998.4.1.25
M3 - Article
AN - SCOPUS:0038609771
SN - 0793-0283
VL - 4
SP - 25
EP - 29
JO - Heterocyclic Communications
JF - Heterocyclic Communications
IS - 1
ER -