A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

Yukinari Sunatsuki; Yukana Kishima; Tamami Kobayashi; Tomoka Yamaguchi; Takayoshi Suzuki; Masaaki Kojima; J. Krzystek; Markku R. Sundberg

doi:10.1039/c1cc12418h

A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

Yukinari Sunatsuki, Yukana Kishima, Tamami Kobayashi, Tomoka Yamaguchi, Takayoshi Suzuki, Masaaki Kojima, J. Krzystek, Markku R. Sundberg

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A series of mononuclear Mn^II, Mn^III, and Mn ^IV complexes was prepared using a single tripodal ligand (H ₃L). Addition of a cation (NH₄⁺, K⁺, Na⁺) to [Mn^IIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the Mn^III complexes.

Original language	English
Pages (from-to)	9149-9151
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	32
DOIs	https://doi.org/10.1039/c1cc12418h
Publication status	Published - Aug 28 2011

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A series of mononuclear MnII, MnIII, and Mn IV complexes was prepared using a single tripodal ligand (H 3L). Addition of a cation (NH4+, K+, Na+) to [MnIIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the MnIII complexes.",

author = "Yukinari Sunatsuki and Yukana Kishima and Tamami Kobayashi and Tomoka Yamaguchi and Takayoshi Suzuki and Masaaki Kojima and J. Krzystek and Sundberg, {Markku R.}",

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T1 - A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

AU - Sunatsuki, Yukinari

AU - Kishima, Yukana

AU - Kobayashi, Tamami

AU - Yamaguchi, Tomoka

AU - Suzuki, Takayoshi

AU - Kojima, Masaaki

AU - Krzystek, J.

AU - Sundberg, Markku R.

PY - 2011/8/28

Y1 - 2011/8/28

N2 - A series of mononuclear MnII, MnIII, and Mn IV complexes was prepared using a single tripodal ligand (H 3L). Addition of a cation (NH4+, K+, Na+) to [MnIIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the MnIII complexes.

AB - A series of mononuclear MnII, MnIII, and Mn IV complexes was prepared using a single tripodal ligand (H 3L). Addition of a cation (NH4+, K+, Na+) to [MnIIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the MnIII complexes.

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JO - Chemical Communications

JF - Chemical Communications

IS - 32

ER -

A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

Abstract

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