Addition reactions of F-alkyl iodides to carbon-carbon double bonds promoted by metallic tin(0)-metal salt systems

Manabu Kuroboshi; Takashi Ishihara

doi:10.1016/S0022-1139(00)82786-4

Addition reactions of F-alkyl iodides to carbon-carbon double bonds promoted by metallic tin(0)-metal salt systems

Manabu Kuroboshi, Takashi Ishihara

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

F-alkyl iodides readily reacted with a variety of alkenes in methanol at room temperature under the influence of metallic tin(0)-silver(I) acetate of metallic tin(0)-copper(I) chloride to afford the corresponding addition products, F- alkylated iodides, in good to excellent yields. This addition reaction was also promoted by the use of a metallic tin(0)- aluminium(0) reagent, though gentle heating was necessary for allowing the reaction to proceed.

Original language	English
Pages (from-to)	299-303
Number of pages	5
Journal	Journal of Fluorine Chemistry
Volume	39
Issue number	2
DOIs	https://doi.org/10.1016/S0022-1139(00)82786-4
Publication status	Published - May 1988
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Environmental Chemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/S0022-1139(00)82786-4

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abstract = "F-alkyl iodides readily reacted with a variety of alkenes in methanol at room temperature under the influence of metallic tin(0)-silver(I) acetate of metallic tin(0)-copper(I) chloride to afford the corresponding addition products, F- alkylated iodides, in good to excellent yields. This addition reaction was also promoted by the use of a metallic tin(0)- aluminium(0) reagent, though gentle heating was necessary for allowing the reaction to proceed.",

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AU - Ishihara, Takashi

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N2 - F-alkyl iodides readily reacted with a variety of alkenes in methanol at room temperature under the influence of metallic tin(0)-silver(I) acetate of metallic tin(0)-copper(I) chloride to afford the corresponding addition products, F- alkylated iodides, in good to excellent yields. This addition reaction was also promoted by the use of a metallic tin(0)- aluminium(0) reagent, though gentle heating was necessary for allowing the reaction to proceed.

AB - F-alkyl iodides readily reacted with a variety of alkenes in methanol at room temperature under the influence of metallic tin(0)-silver(I) acetate of metallic tin(0)-copper(I) chloride to afford the corresponding addition products, F- alkylated iodides, in good to excellent yields. This addition reaction was also promoted by the use of a metallic tin(0)- aluminium(0) reagent, though gentle heating was necessary for allowing the reaction to proceed.

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Addition reactions of F-alkyl iodides to carbon-carbon double bonds promoted by metallic tin(0)-metal salt systems

Abstract

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