Aliphatic claisen rearrangement promoted by organoaluminium compounds

Kazuhiko Takai, Ichiro Mori, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journalArticlepeer-review

70 Citations (Scopus)


Treatment of allyl vinyl ether derivatives with organoaluminiumamphoteric reagent, R3Al or R2AlSPn, results in the title reaction at room temperature under uptake of R, H, or SPh as a nucleophile on the aldehydic carbon.

Original languageEnglish
Pages (from-to)3985-3988
Number of pages4
JournalTetrahedron Letters
Issue number40
Publication statusPublished - 1981
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry


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