Alkylidenation of carbonyl compounds with gem-dizincioalkanes mediated with titanium dichloride

Seijiro Matsubara, Tsuyoshi Mizuno, Tasuyuiki Otake, Masami Kobata, Kiitiro Utimoto, Kazuhiko Takai

Research output: Contribution to journalArticlepeer-review

50 Citations (Scopus)

Abstract

Olefination of carbonyl compounds with gem-dizincio-alkanes, bis(iodozincio)methane, 1,1-bis(iodozincio)ethane, and bis(bromozincio)methyltrimethylsilane, afforded the corresponding olefins in good to excellent yields.

Original languageEnglish
Pages (from-to)1369-1371
Number of pages3
JournalSynlett
Issue number12
DOIs
Publication statusPublished - Dec 1998

ASJC Scopus subject areas

  • Organic Chemistry

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