Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

Masahito Murai; Shotaro Yoshida; Koji Miki; Kouichi Ohe

doi:10.1039/b924752a

Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

Masahito Murai, Shotaro Yoshida, Koji Miki, Kouichi Ohe

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl₂ afforded the α-alkylidene-N-furylimines with high stereoselectivities.

Original language	English
Pages (from-to)	3366-3368
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	19
DOIs	https://doi.org/10.1039/b924752a
Publication status	Published - 2010

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds",

abstract = "The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl2 afforded the α-alkylidene-N-furylimines with high stereoselectivities.",

author = "Masahito Murai and Shotaro Yoshida and Koji Miki and Kouichi Ohe",

year = "2010",

doi = "10.1039/b924752a",

language = "English",

volume = "46",

pages = "3366--3368",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

AU - Murai, Masahito

AU - Yoshida, Shotaro

AU - Miki, Koji

AU - Ohe, Kouichi

PY - 2010

Y1 - 2010

N2 - The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl2 afforded the α-alkylidene-N-furylimines with high stereoselectivities.

AB - The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl2 afforded the α-alkylidene-N-furylimines with high stereoselectivities.

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U2 - 10.1039/b924752a

DO - 10.1039/b924752a

M3 - Article

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AN - SCOPUS:77951997602

SN - 1359-7345

VL - 46

SP - 3366

EP - 3368

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

Abstract

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