Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)

Takayoshi Suzuki; Hideo D. Takagi; Kazuo Kashiwabara

doi:10.1107/S0108270101018406

Bis(μ-N, N-dimethyldithiocarbamato-κ³ S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ²S, S′)cobalt(III)] bis(hexafluorophosphate)

Takayoshi Suzuki, Hideo D. Takagi, Kazuo Kashiwabara

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co₂(C₃H₆NS₂)₄] (C₈H₁₁O₂P)₂](PF₆) ₂ were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C₂ symmetry and a dinuclear structure.

Original language	English
Pages (from-to)	m95-m97
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	2
DOIs	https://doi.org/10.1107/S0108270101018406
Publication status	Published - Feb 2002
Externally published	Yes

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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10.1107/S0108270101018406

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Bis(μ-N, N-dimethyldithiocarbamato-κ³ S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ²S, S′)cobalt(III)] bis(hexafluorophosphate). / Suzuki, Takayoshi; Takagi, Hideo D.; Kashiwabara, Kazuo.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, No. 2, 02.2002, p. m95-m97.

Research output: Contribution to journal › Article › peer-review

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title = "Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)",

abstract = "Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.",

author = "Takayoshi Suzuki and Takagi, {Hideo D.} and Kazuo Kashiwabara",

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T1 - Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)

AU - Suzuki, Takayoshi

AU - Takagi, Hideo D.

AU - Kashiwabara, Kazuo

PY - 2002/2

Y1 - 2002/2

N2 - Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

AB - Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

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JF - Acta Crystallographica Section C: Crystal Structure Communications

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Bis(μ-N, N-dimethyldithiocarbamato-κ³ S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ²S, S′)cobalt(III)] bis(hexafluorophosphate)

Abstract

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