TY - JOUR
T1 - Bis[-2-(aminosulfanyl)pyridine(1-)]bis-[(5-penta-methyl-cyclo- penta-dien-yl)iridium(III)] diiodide
AU - Sekioka, Yusuke
AU - Suzuki, Takayoshi
PY - 2009
Y1 - 2009
N2 - In the title dinuclear iridium(III) complex, [Ir2(C10H15) 2(C5H5N2S)2]I2, the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1-) [(2-py)SNH] ligands in a-(2-py)SNH-2 N(py),N(NH):N(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir2N 2 ring with an Ir- N(py) bond length of 2.085 (9) Å and bridging Ir- N(NH) bonds of 2.110 (9) and 2.113 (9) Å. The two (2-py)S units have mutually anti configurations with respect to the Ir2N2 ring.
AB - In the title dinuclear iridium(III) complex, [Ir2(C10H15) 2(C5H5N2S)2]I2, the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1-) [(2-py)SNH] ligands in a-(2-py)SNH-2 N(py),N(NH):N(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir2N 2 ring with an Ir- N(py) bond length of 2.085 (9) Å and bridging Ir- N(NH) bonds of 2.110 (9) and 2.113 (9) Å. The two (2-py)S units have mutually anti configurations with respect to the Ir2N2 ring.
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U2 - 10.1107/S1600536809037167
DO - 10.1107/S1600536809037167
M3 - Article
C2 - 21577749
AN - SCOPUS:70349777534
SN - 1600-5368
VL - 65
SP - m1229-m1230
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 10
ER -