Bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]-dimethylaluminum catalyst for effecting Tishchenko reaction

Seiji Shirakawa; Jun Takai; Kouji Sasaki; Tomoya Miura; Keiji Maruoka

doi:10.3987/com-02-s14

Bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]-dimethylaluminum catalyst for effecting Tishchenko reaction

Seiji Shirakawa, Jun Takai, Kouji Sasaki, Tomoya Miura, Keiji Maruoka

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

High-speed Tishchenko reaction of various aldehydes can be realized by using a bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]dimethylaluminum catalyst, which is readily prepared by treatment of tris(2,6-diphenylbenzyl)silanol with trimethylaluminum.

Original language	English
Pages (from-to)	57-61
Number of pages	5
Journal	Heterocycles
Volume	59
Issue number	1
DOIs	https://doi.org/10.3987/com-02-s14
Publication status	Published - Jan 1 2003
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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title = "Bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]-dimethylaluminum catalyst for effecting Tishchenko reaction",

abstract = "High-speed Tishchenko reaction of various aldehydes can be realized by using a bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]dimethylaluminum catalyst, which is readily prepared by treatment of tris(2,6-diphenylbenzyl)silanol with trimethylaluminum.",

author = "Seiji Shirakawa and Jun Takai and Kouji Sasaki and Tomoya Miura and Keiji Maruoka",

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AU - Shirakawa, Seiji

AU - Takai, Jun

AU - Sasaki, Kouji

AU - Miura, Tomoya

AU - Maruoka, Keiji

PY - 2003/1/1

Y1 - 2003/1/1

N2 - High-speed Tishchenko reaction of various aldehydes can be realized by using a bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]dimethylaluminum catalyst, which is readily prepared by treatment of tris(2,6-diphenylbenzyl)silanol with trimethylaluminum.

AB - High-speed Tishchenko reaction of various aldehydes can be realized by using a bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]dimethylaluminum catalyst, which is readily prepared by treatment of tris(2,6-diphenylbenzyl)silanol with trimethylaluminum.

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AN - SCOPUS:0037226398

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ER -

Bowl-shaped [tris(2,6-diphenylbenzyl)siloxy]-dimethylaluminum catalyst for effecting Tishchenko reaction

Abstract

ASJC Scopus subject areas

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