TY - JOUR
T1 - Bridging the gap between small clusters and nanodroplets
T2 - Spectroscopic study and computer simulation of carbon dioxide solvated with helium atoms
AU - Tang, J.
AU - McKellar, A. R.W.
AU - Mezzacapo, F.
AU - Moroni, S.
PY - 2004/4/9
Y1 - 2004/4/9
N2 - The high resolution infrared spectra of HeN-CO2 cluster with N up to 17 in the region of the CO2 v3 fundamental band was studied. The He density profiles for HeN-CO 2 with N=5 and 6 were compared with those of HeN-carbonyl sulfide (OCS) and HeN-N2O. The variation of the vibrational band origin, vO, with cluster size, which includes a comparison with HeN-OCS and HeN-N2O, was also shown. The measured and calculated values of the rotational constant B and centrifugal distortion D were also compared.
AB - The high resolution infrared spectra of HeN-CO2 cluster with N up to 17 in the region of the CO2 v3 fundamental band was studied. The He density profiles for HeN-CO 2 with N=5 and 6 were compared with those of HeN-carbonyl sulfide (OCS) and HeN-N2O. The variation of the vibrational band origin, vO, with cluster size, which includes a comparison with HeN-OCS and HeN-N2O, was also shown. The measured and calculated values of the rotational constant B and centrifugal distortion D were also compared.
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U2 - 10.1103/PhysRevLett.92.145503
DO - 10.1103/PhysRevLett.92.145503
M3 - Article
C2 - 15089550
AN - SCOPUS:2542426961
SN - 0031-9007
VL - 92
SP - 145503-1-145503-4
JO - Physical Review Letters
JF - Physical Review Letters
IS - 14
M1 - 145503
ER -