Catalytic, high-speed Tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst

Takashi Ooi; Tomoya Miura; Keisuke Takaya; Keiji Maruoka

doi:10.1016/S0040-4039(99)01555-5

Catalytic, high-speed Tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst

Takashi Ooi, Tomoya Miura, Keisuke Takaya, Keiji Maruoka

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

Exceedingly high-speed Tishchenko reaction of various aldehydes can be realized by using a powerful, bidentate aluminum catalyst. This catalytic system is also applicable to the highly stereoselective intramolecular Tishchenko reduction of β-hydroxy ketones.

Original language	English
Pages (from-to)	7695-7698
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	43
DOIs	https://doi.org/10.1016/S0040-4039(99)01555-5
Publication status	Published - Oct 22 1999
Externally published	Yes

Keywords

Aldehydes
Bidentate aluminum alkoxides
Carboxylic esters
Tishchenko reaction

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(99)01555-5

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title = "Catalytic, high-speed Tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst",

abstract = "Exceedingly high-speed Tishchenko reaction of various aldehydes can be realized by using a powerful, bidentate aluminum catalyst. This catalytic system is also applicable to the highly stereoselective intramolecular Tishchenko reduction of β-hydroxy ketones.",

keywords = "Aldehydes, Bidentate aluminum alkoxides, Carboxylic esters, Tishchenko reaction",

author = "Takashi Ooi and Tomoya Miura and Keisuke Takaya and Keiji Maruoka",

note = "Funding Information: This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas (No. 706: Dynamic Control of Stereochemistry) from the Ministry of Education, Science, Sports, and Culture, Japan. T.M. thanks the Japan Society for the Promotion of Science for Young Scientists for Research Fellowships.",

year = "1999",

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doi = "10.1016/S0040-4039(99)01555-5",

language = "English",

volume = "40",

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journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Catalytic, high-speed Tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst

AU - Ooi, Takashi

AU - Miura, Tomoya

AU - Takaya, Keisuke

AU - Maruoka, Keiji

N1 - Funding Information: This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas (No. 706: Dynamic Control of Stereochemistry) from the Ministry of Education, Science, Sports, and Culture, Japan. T.M. thanks the Japan Society for the Promotion of Science for Young Scientists for Research Fellowships.

PY - 1999/10/22

Y1 - 1999/10/22

N2 - Exceedingly high-speed Tishchenko reaction of various aldehydes can be realized by using a powerful, bidentate aluminum catalyst. This catalytic system is also applicable to the highly stereoselective intramolecular Tishchenko reduction of β-hydroxy ketones.

AB - Exceedingly high-speed Tishchenko reaction of various aldehydes can be realized by using a powerful, bidentate aluminum catalyst. This catalytic system is also applicable to the highly stereoselective intramolecular Tishchenko reduction of β-hydroxy ketones.

KW - Aldehydes

KW - Bidentate aluminum alkoxides

KW - Carboxylic esters

KW - Tishchenko reaction

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DO - 10.1016/S0040-4039(99)01555-5

M3 - Article

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SN - 0040-4039

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 43

ER -

Catalytic, high-speed Tishchenko reaction using (2,7-dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a powerful bidentate catalyst

Abstract

Keywords

ASJC Scopus subject areas

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