TY - JOUR
T1 - Catena-poly[[[N,N′-bis-(3-methoxy-benzyl-idene)ethyl-enediamine] copper(I)]-μ-thio-cyanato-k2 N:S]
AU - Khalaji, Aliakbar Dehno
AU - Hadadzadeh, Hassan
AU - Gotoh, Kazuma
AU - Ishida, Hiroyuki
PY - 2008
Y1 - 2008
N2 - In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.
AB - In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.
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U2 - 10.1107/S1600536808041925
DO - 10.1107/S1600536808041925
M3 - Article
C2 - 21581537
AN - SCOPUS:58149468054
SN - 1600-5368
VL - 65
SP - m70
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 1
ER -