Chemical studies on rutherfordium (Rf) at JAERI

Y. Nagame; K. Tsukada; M. Asai; A. Toyoshima; K. Akiyama; Y. Ishii; T. Kaneko-Sato; M. Hirata; I. Nishinaka; S. Ichikawa; H. Haba; S. Enomoto; K. Matsuo; D. Saika; Y. Kitamoto; H. Hasegawa; Y. Tani; W. Sato; A. Shinohara; M. Ito; J. Saito; S. Goto; H. Kudo; H. Kikunaga; N. Kinoshita; A. Yokoyama; K. Sueki; Y. Oura; H. Nakahara; M. Sakama; M. Schädel; W. Brüchle; J. V. Kratz

doi:10.1524/ract.2005.93.9-10.519

Chemical studies on rutherfordium (Rf) at JAERI

Y. Nagame, K. Tsukada, M. Asai, A. Toyoshima, K. Akiyama, Y. Ishii, T. Kaneko-Sato, M. Hirata, I. Nishinaka, S. Ichikawa, H. Haba, S. Enomoto, K. Matsuo, D. Saika, Y. Kitamoto, H. Hasegawa, Y. Tani, W. Sato, A. Shinohara, M. ItoJ. Saito, S. Goto, H. Kudo, H. Kikunaga, N. Kinoshita, A. Yokoyama, K. Sueki, Y. Oura, H. Nakahara, M. Sakama, M. Schädel, W. Brüchle, J. V. Kratz

School of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Chemical studies on element 104, rutherfordium (Rf), at JAERI (Japan Atomic Energy Research Institute) are reviewed. The transactinide nuclide ²⁶¹Rf has been produced in the reaction ²⁴⁸Cm( ¹⁸O, 5n) at the JAERI tandem accelerator with the production cross section of about 13 nb. On-line anion-exchange experiments on Rf together with the lighter homologues, group-4 elements Zr and Hf, in acidic solutions have been conducted with a rapid ion-exchange separation apparatus. From the systematic study of the anion-exchange behavior of Rf, it has been found that the properties of Rf in HCl and HNO₃ solutions are quite similar to those of Zr and Hf, definitely confirming that Rf is a member of the group-4 elements. However, we have observed an unexpected chemical behavior of Rf in HF solutions; the fluoride complex formation of Rf is significantly different from those of the homologues. Prospects of extending chemical studies on transactinide elements in the near future at JAERI are briefly considered.

Original language	English
Pages (from-to)	519-526
Number of pages	8
Journal	Radiochimica Acta
Volume	93
Issue number	9-10
DOIs	https://doi.org/10.1524/ract.2005.93.9-10.519
Publication status	Published - 2005

Keywords

Anion-exchange behavior
Atom-at-a-time chemistry
Distribution coefficient K
Elution curve
Production of Rf
Rutherfordium

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1524/ract.2005.93.9-10.519

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Nagame, Y., Tsukada, K., Asai, M., Toyoshima, A., Akiyama, K., Ishii, Y., Kaneko-Sato, T., Hirata, M., Nishinaka, I., Ichikawa, S., Haba, H., Enomoto, S., Matsuo, K., Saika, D., Kitamoto, Y., Hasegawa, H., Tani, Y., Sato, W., Shinohara, A., ... Kratz, J. V. (2005). Chemical studies on rutherfordium (Rf) at JAERI. Radiochimica Acta, 93(9-10), 519-526. https://doi.org/10.1524/ract.2005.93.9-10.519

Nagame, Y, Tsukada, K, Asai, M, Toyoshima, A, Akiyama, K, Ishii, Y, Kaneko-Sato, T, Hirata, M, Nishinaka, I, Ichikawa, S, Haba, H, Enomoto, S, Matsuo, K, Saika, D, Kitamoto, Y, Hasegawa, H, Tani, Y, Sato, W, Shinohara, A, Ito, M, Saito, J, Goto, S, Kudo, H, Kikunaga, H, Kinoshita, N, Yokoyama, A, Sueki, K, Oura, Y, Nakahara, H, Sakama, M, Schädel, M, Brüchle, W & Kratz, JV 2005, 'Chemical studies on rutherfordium (Rf) at JAERI', Radiochimica Acta, vol. 93, no. 9-10, pp. 519-526. https://doi.org/10.1524/ract.2005.93.9-10.519

@article{3c42f4b9b54c4d529dcc37d31c9214e7,

title = "Chemical studies on rutherfordium (Rf) at JAERI",

abstract = "Chemical studies on element 104, rutherfordium (Rf), at JAERI (Japan Atomic Energy Research Institute) are reviewed. The transactinide nuclide 261Rf has been produced in the reaction 248Cm( 18O, 5n) at the JAERI tandem accelerator with the production cross section of about 13 nb. On-line anion-exchange experiments on Rf together with the lighter homologues, group-4 elements Zr and Hf, in acidic solutions have been conducted with a rapid ion-exchange separation apparatus. From the systematic study of the anion-exchange behavior of Rf, it has been found that the properties of Rf in HCl and HNO3 solutions are quite similar to those of Zr and Hf, definitely confirming that Rf is a member of the group-4 elements. However, we have observed an unexpected chemical behavior of Rf in HF solutions; the fluoride complex formation of Rf is significantly different from those of the homologues. Prospects of extending chemical studies on transactinide elements in the near future at JAERI are briefly considered.",

keywords = "Anion-exchange behavior, Atom-at-a-time chemistry, Distribution coefficient K, Elution curve, Production of Rf, Rutherfordium",

author = "Y. Nagame and K. Tsukada and M. Asai and A. Toyoshima and K. Akiyama and Y. Ishii and T. Kaneko-Sato and M. Hirata and I. Nishinaka and S. Ichikawa and H. Haba and S. Enomoto and K. Matsuo and D. Saika and Y. Kitamoto and H. Hasegawa and Y. Tani and W. Sato and A. Shinohara and M. Ito and J. Saito and S. Goto and H. Kudo and H. Kikunaga and N. Kinoshita and A. Yokoyama and K. Sueki and Y. Oura and H. Nakahara and M. Sakama and M. Sch{\"a}del and W. Br{\"u}chle and Kratz, {J. V.}",

note = "Funding Information: Acknowledgment. We would like to acknowledge the crew of the JAERI tandem accelerator for providing the stable 18O beam. This work was supported in part by the JAERI-University Collaboration Research Program and by the Program on the Scientific Cooperation between JAERI and GSI in Research and Development in the Field of Ion Beam Application.",

year = "2005",

doi = "10.1524/ract.2005.93.9-10.519",

language = "English",

volume = "93",

pages = "519--526",

journal = "Radiochimica Acta",

issn = "0033-8230",

publisher = "R. Oldenbourg",

number = "9-10",

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TY - JOUR

T1 - Chemical studies on rutherfordium (Rf) at JAERI

AU - Nagame, Y.

AU - Tsukada, K.

AU - Asai, M.

AU - Toyoshima, A.

AU - Akiyama, K.

AU - Ishii, Y.

AU - Kaneko-Sato, T.

AU - Hirata, M.

AU - Nishinaka, I.

AU - Ichikawa, S.

AU - Haba, H.

AU - Enomoto, S.

AU - Matsuo, K.

AU - Saika, D.

AU - Kitamoto, Y.

AU - Hasegawa, H.

AU - Tani, Y.

AU - Sato, W.

AU - Shinohara, A.

AU - Ito, M.

AU - Saito, J.

AU - Goto, S.

AU - Kudo, H.

AU - Kikunaga, H.

AU - Kinoshita, N.

AU - Yokoyama, A.

AU - Sueki, K.

AU - Oura, Y.

AU - Nakahara, H.

AU - Sakama, M.

AU - Schädel, M.

AU - Brüchle, W.

AU - Kratz, J. V.

N1 - Funding Information: Acknowledgment. We would like to acknowledge the crew of the JAERI tandem accelerator for providing the stable 18O beam. This work was supported in part by the JAERI-University Collaboration Research Program and by the Program on the Scientific Cooperation between JAERI and GSI in Research and Development in the Field of Ion Beam Application.

PY - 2005

Y1 - 2005

N2 - Chemical studies on element 104, rutherfordium (Rf), at JAERI (Japan Atomic Energy Research Institute) are reviewed. The transactinide nuclide 261Rf has been produced in the reaction 248Cm( 18O, 5n) at the JAERI tandem accelerator with the production cross section of about 13 nb. On-line anion-exchange experiments on Rf together with the lighter homologues, group-4 elements Zr and Hf, in acidic solutions have been conducted with a rapid ion-exchange separation apparatus. From the systematic study of the anion-exchange behavior of Rf, it has been found that the properties of Rf in HCl and HNO3 solutions are quite similar to those of Zr and Hf, definitely confirming that Rf is a member of the group-4 elements. However, we have observed an unexpected chemical behavior of Rf in HF solutions; the fluoride complex formation of Rf is significantly different from those of the homologues. Prospects of extending chemical studies on transactinide elements in the near future at JAERI are briefly considered.

AB - Chemical studies on element 104, rutherfordium (Rf), at JAERI (Japan Atomic Energy Research Institute) are reviewed. The transactinide nuclide 261Rf has been produced in the reaction 248Cm( 18O, 5n) at the JAERI tandem accelerator with the production cross section of about 13 nb. On-line anion-exchange experiments on Rf together with the lighter homologues, group-4 elements Zr and Hf, in acidic solutions have been conducted with a rapid ion-exchange separation apparatus. From the systematic study of the anion-exchange behavior of Rf, it has been found that the properties of Rf in HCl and HNO3 solutions are quite similar to those of Zr and Hf, definitely confirming that Rf is a member of the group-4 elements. However, we have observed an unexpected chemical behavior of Rf in HF solutions; the fluoride complex formation of Rf is significantly different from those of the homologues. Prospects of extending chemical studies on transactinide elements in the near future at JAERI are briefly considered.

KW - Anion-exchange behavior

KW - Atom-at-a-time chemistry

KW - Distribution coefficient K

KW - Elution curve

KW - Production of Rf

KW - Rutherfordium

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DO - 10.1524/ract.2005.93.9-10.519

M3 - Article

AN - SCOPUS:27744451886

SN - 0033-8230

VL - 93

SP - 519

EP - 526

JO - Radiochimica Acta

JF - Radiochimica Acta

IS - 9-10

ER -

Chemical studies on rutherfordium (Rf) at JAERI

Abstract

Keywords

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