Circular polarization of photochemiluminescence from the photoisomer of a conformationally fixed 2,11-diaza[3.3](9,10)anthracenoparacyclophane derivative

Hideki Okamoto; Harry P.J.M. Dekkers; Kyosuke Satake; Masaru Kimura

doi:10.1039/a801296b

Circular polarization of photochemiluminescence from the photoisomer of a conformationally fixed 2,11-diaza[3.3](9,10)anthracenoparacyclophane derivative

Hideki Okamoto, Harry P.J.M. Dekkers, Kyosuke Satake, Masaru Kimura

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The conformation of 2,11-diaza[3.3](9,10)anthracenoparacyclophane 1, which underwent photointerconversion with isomer 2, was fixed with the aid of a chiral camphanic auxiliary to have molecular chirality, and the photochemiluminescence from the modified 2a was circularly polarized reflecting the chirality of the emitting state.

Original language	English
Pages (from-to)	1049-1050
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/a801296b
Publication status	Published - May 7 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a801296b

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abstract = "The conformation of 2,11-diaza[3.3](9,10)anthracenoparacyclophane 1, which underwent photointerconversion with isomer 2, was fixed with the aid of a chiral camphanic auxiliary to have molecular chirality, and the photochemiluminescence from the modified 2a was circularly polarized reflecting the chirality of the emitting state.",

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AU - Okamoto, Hideki

AU - Dekkers, Harry P.J.M.

AU - Satake, Kyosuke

AU - Kimura, Masaru

PY - 1998/5/7

Y1 - 1998/5/7

N2 - The conformation of 2,11-diaza[3.3](9,10)anthracenoparacyclophane 1, which underwent photointerconversion with isomer 2, was fixed with the aid of a chiral camphanic auxiliary to have molecular chirality, and the photochemiluminescence from the modified 2a was circularly polarized reflecting the chirality of the emitting state.

AB - The conformation of 2,11-diaza[3.3](9,10)anthracenoparacyclophane 1, which underwent photointerconversion with isomer 2, was fixed with the aid of a chiral camphanic auxiliary to have molecular chirality, and the photochemiluminescence from the modified 2a was circularly polarized reflecting the chirality of the emitting state.

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Circular polarization of photochemiluminescence from the photoisomer of a conformationally fixed 2,11-diaza[3.3](9,10)anthracenoparacyclophane derivative

Abstract

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