Cobalt(III) complex [CoL3] derived from an asymmetric bidentate schiff base ligand L (L=(5-bromo-2-hydroxybenzyl-2-furylmethyl)-imine): Synthesis, characterization and crystal structure

Aliakbar D. Khalaji; Sepideh Maghsodlou Rad; Gholamhossein Grivani; Morteza Rezaei; Kazuma Gotoh; Hiroyuki Ishida

doi:10.1002/cjoc.201180289

Cobalt(III) complex [CoL₃] derived from an asymmetric bidentate schiff base ligand L (L=(5-bromo-2-hydroxybenzyl-2-furylmethyl)-imine): Synthesis, characterization and crystal structure

Aliakbar D. Khalaji, Sepideh Maghsodlou Rad, Gholamhossein Grivani, Morteza Rezaei, Kazuma Gotoh, Hiroyuki Ishida

School of Science

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Cobalt(III) complex [CoL₃], where L=(5-bromo-2-hydroxybenzyl-2- furylmethyl)imine, has been synthesized by reacting cobalt(II) nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL₃] was determined by X-ray crystallography from single crystal data. It crystallizes in the triclinic space group P1̄ with unit cell parameters:a=9.6644(10) Å,b=11.5657(11) Å,c=16.5809(17) Å,α=102.833(4)°,β=102.999(3)°, γ=105.480(3)°,V=1659.9(3) Å³andZ=2. Thermal decomposition of [CoL₃] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.

Original language	English
Pages (from-to)	1613-1616
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	29
Issue number	8
DOIs	https://doi.org/10.1002/cjoc.201180289
Publication status	Published - Aug 1 2011

Keywords

Cobat(III)
crystal structure
spectroscopy
thermogravimetry

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/cjoc.201180289

Cite this

Cobalt(III) complex [CoL₃] derived from an asymmetric bidentate schiff base ligand L (L=(5-bromo-2-hydroxybenzyl-2-furylmethyl)-imine): Synthesis, characterization and crystal structure. / Khalaji, Aliakbar D.; Maghsodlou Rad, Sepideh; Grivani, Gholamhossein et al.
In: Chinese Journal of Chemistry, Vol. 29, No. 8, 01.08.2011, p. 1613-1616.

Research output: Contribution to journal › Article › peer-review

Khalaji, AD, Maghsodlou Rad, S, Grivani, G, Rezaei, M, Gotoh, K & Ishida, H 2011, 'Cobalt(III) complex [CoL₃] derived from an asymmetric bidentate schiff base ligand L (L=(5-bromo-2-hydroxybenzyl-2-furylmethyl)-imine): Synthesis, characterization and crystal structure', Chinese Journal of Chemistry, vol. 29, no. 8, pp. 1613-1616. https://doi.org/10.1002/cjoc.201180289

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abstract = "Cobalt(III) complex [CoL3], where L=(5-bromo-2-hydroxybenzyl-2- furylmethyl)imine, has been synthesized by reacting cobalt(II) nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL3] was determined by X-ray crystallography from single crystal data. It crystallizes in the triclinic space group P{\=1} with unit cell parameters:a=9.6644(10) {\AA},b=11.5657(11) {\AA},c=16.5809(17) {\AA},α=102.833(4)°,β=102.999(3)°, γ=105.480(3)°,V=1659.9(3) {\AA}3andZ=2. Thermal decomposition of [CoL3] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.",

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AU - Khalaji, Aliakbar D.

AU - Maghsodlou Rad, Sepideh

AU - Grivani, Gholamhossein

AU - Rezaei, Morteza

AU - Gotoh, Kazuma

AU - Ishida, Hiroyuki

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N2 - Cobalt(III) complex [CoL3], where L=(5-bromo-2-hydroxybenzyl-2- furylmethyl)imine, has been synthesized by reacting cobalt(II) nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL3] was determined by X-ray crystallography from single crystal data. It crystallizes in the triclinic space group P1̄ with unit cell parameters:a=9.6644(10) Å,b=11.5657(11) Å,c=16.5809(17) Å,α=102.833(4)°,β=102.999(3)°, γ=105.480(3)°,V=1659.9(3) Å3andZ=2. Thermal decomposition of [CoL3] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.

AB - Cobalt(III) complex [CoL3], where L=(5-bromo-2-hydroxybenzyl-2- furylmethyl)imine, has been synthesized by reacting cobalt(II) nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL3] was determined by X-ray crystallography from single crystal data. It crystallizes in the triclinic space group P1̄ with unit cell parameters:a=9.6644(10) Å,b=11.5657(11) Å,c=16.5809(17) Å,α=102.833(4)°,β=102.999(3)°, γ=105.480(3)°,V=1659.9(3) Å3andZ=2. Thermal decomposition of [CoL3] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.

KW - Cobat(III)

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KW - spectroscopy

KW - thermogravimetry

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