Conglomerate crystallization, chiral recognition and spin-crossover in a host-guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3- (guest)

Yukinari Sunatsuki; Sho Miyahara; Yuu Sasaki; Takayoshi Suzuki; Masaaki Kojima; Naohide Matsumoto

doi:10.1039/c2ce25612f

Conglomerate crystallization, chiral recognition and spin-crossover in a host-guest complex consisting of Fe^III complexes (host) and [Cr(ox)₃]^3- (guest)

Yukinari Sunatsuki, Sho Miyahara, Yuu Sasaki, Takayoshi Suzuki, Masaaki Kojima, Naohide Matsumoto

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A host-guest complex, [Fe^III(H₃L)][Fe ^III(L)][Cr^III(ox)₃]·3H₂O (1), where H₃L and L^3- serve as hexadentate ligands, was prepared. In 1, three properties are united: the homochiral assembly of chiral [Fe^III(H₃L)]³⁺ and [Fe^III(L)] into a conglomerate structure, the chiral recognition of the host Fe^III assembly to the guest [Cr^III(ox)₃]^3- and the spin-crossover of [Fe^III(H₃L)]³⁺.

Original language	English
Pages (from-to)	6377-6380
Number of pages	4
Journal	CrystEngComm
Volume	14
Issue number	20
DOIs	https://doi.org/10.1039/c2ce25612f
Publication status	Published - Oct 21 2012

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Conglomerate crystallization, chiral recognition and spin-crossover in a host-guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3- (guest)",

abstract = "A host-guest complex, [FeIII(H3L)][Fe III(L)][CrIII(ox)3]·3H2O (1), where H3L and L3- serve as hexadentate ligands, was prepared. In 1, three properties are united: the homochiral assembly of chiral [FeIII(H3L)]3+ and [FeIII(L)] into a conglomerate structure, the chiral recognition of the host FeIII assembly to the guest [CrIII(ox)3]3- and the spin-crossover of [FeIII(H3L)]3+.",

author = "Yukinari Sunatsuki and Sho Miyahara and Yuu Sasaki and Takayoshi Suzuki and Masaaki Kojima and Naohide Matsumoto",

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T1 - Conglomerate crystallization, chiral recognition and spin-crossover in a host-guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3- (guest)

AU - Sunatsuki, Yukinari

AU - Miyahara, Sho

AU - Sasaki, Yuu

AU - Suzuki, Takayoshi

AU - Kojima, Masaaki

AU - Matsumoto, Naohide

PY - 2012/10/21

Y1 - 2012/10/21

N2 - A host-guest complex, [FeIII(H3L)][Fe III(L)][CrIII(ox)3]·3H2O (1), where H3L and L3- serve as hexadentate ligands, was prepared. In 1, three properties are united: the homochiral assembly of chiral [FeIII(H3L)]3+ and [FeIII(L)] into a conglomerate structure, the chiral recognition of the host FeIII assembly to the guest [CrIII(ox)3]3- and the spin-crossover of [FeIII(H3L)]3+.

AB - A host-guest complex, [FeIII(H3L)][Fe III(L)][CrIII(ox)3]·3H2O (1), where H3L and L3- serve as hexadentate ligands, was prepared. In 1, three properties are united: the homochiral assembly of chiral [FeIII(H3L)]3+ and [FeIII(L)] into a conglomerate structure, the chiral recognition of the host FeIII assembly to the guest [CrIII(ox)3]3- and the spin-crossover of [FeIII(H3L)]3+.

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Conglomerate crystallization, chiral recognition and spin-crossover in a host-guest complex consisting of Fe^III complexes (host) and [Cr(ox)₃]^3- (guest)

Abstract

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