Convenient rearrangement reaction of 2-chloroglycidic esters by PPh 3: A new synthetic method of 3-chloro-2-keto esters

Takuzo Komiyama; Yutaka Takaguchi; Sadao Tsuboi

doi:10.1080/00397910600764618

Convenient rearrangement reaction of 2-chloroglycidic esters by PPh ₃: A new synthetic method of 3-chloro-2-keto esters

Takuzo Komiyama, Yutaka Takaguchi, Sadao Tsuboi

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A convenient rearrangement reaction of 2-chloroglycidic esters is reported. Treatment of 2-chloroglycidic esters with PPh₃ under refluxing condition results in the formation of 3-chloro-2-keto esters in good to reasonable yields.

Original language	English
Pages (from-to)	2621-2625
Number of pages	5
Journal	Synthetic Communications
Volume	36
Issue number	18
DOIs	https://doi.org/10.1080/00397910600764618
Publication status	Published - Sept 1 2006

Keywords

2-Chloroglycidic ester
Darzens condensation
Dichloroacetate
Rearrangement reaction

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1080/00397910600764618

Cite this

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title = "Convenient rearrangement reaction of 2-chloroglycidic esters by PPh 3: A new synthetic method of 3-chloro-2-keto esters",

abstract = "A convenient rearrangement reaction of 2-chloroglycidic esters is reported. Treatment of 2-chloroglycidic esters with PPh3 under refluxing condition results in the formation of 3-chloro-2-keto esters in good to reasonable yields.",

keywords = "2-Chloroglycidic ester, Darzens condensation, Dichloroacetate, Rearrangement reaction",

author = "Takuzo Komiyama and Yutaka Takaguchi and Sadao Tsuboi",

year = "2006",

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T2 - A new synthetic method of 3-chloro-2-keto esters

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AU - Takaguchi, Yutaka

AU - Tsuboi, Sadao

PY - 2006/9/1

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AB - A convenient rearrangement reaction of 2-chloroglycidic esters is reported. Treatment of 2-chloroglycidic esters with PPh3 under refluxing condition results in the formation of 3-chloro-2-keto esters in good to reasonable yields.

KW - 2-Chloroglycidic ester

KW - Darzens condensation

KW - Dichloroacetate

KW - Rearrangement reaction

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