Coordination of aluminum in new glasses of the system Al-Cd-O-F

Osaka Akiyoshi; Fu Jie; Takada Jun; Miura Yoshinari; Maekawa Hideki

doi:10.1016/0167-577X(91)90118-P

Coordination of aluminum in new glasses of the system Al-Cd-O-F

Osaka Akiyoshi, Fu Jie, Takada Jun, Miura Yoshinari, Maekawa Hideki

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

New glasses were obtained in the system Al-Cd-Pb-O-F and investigated by ²⁷Al magic angle spinning nuclear magnetic resonance spectroscopy. The chemical shift with respect to [Al(H₂O)₆]³⁺ indicated the presence of both four- and six-coordinated Al atoms (Al(4) and Al(6) units) in the glasses. Not only the fraction of Al (6) but also the number of fluorine atoms taking part in Al(6) increased with increasing fluorine content.

Original language	English
Pages (from-to)	369-372
Number of pages	4
Journal	Materials Letters
Volume	12
Issue number	5
DOIs	https://doi.org/10.1016/0167-577X(91)90118-P
Publication status	Published - Dec 1991
Externally published	Yes

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1016/0167-577X(91)90118-P

Cite this

@article{75ae203d9f3b4feda5a69a579e3aee0c,

title = "Coordination of aluminum in new glasses of the system Al-Cd-O-F",

abstract = "New glasses were obtained in the system Al-Cd-Pb-O-F and investigated by 27Al magic angle spinning nuclear magnetic resonance spectroscopy. The chemical shift with respect to [Al(H2O)6]3+ indicated the presence of both four- and six-coordinated Al atoms (Al(4) and Al(6) units) in the glasses. Not only the fraction of Al (6) but also the number of fluorine atoms taking part in Al(6) increased with increasing fluorine content.",

author = "Osaka Akiyoshi and Fu Jie and Takada Jun and Miura Yoshinari and Maekawa Hideki",

year = "1991",

month = dec,

doi = "10.1016/0167-577X(91)90118-P",

language = "English",

volume = "12",

pages = "369--372",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier",

number = "5",

}

TY - JOUR

T1 - Coordination of aluminum in new glasses of the system Al-Cd-O-F

AU - Akiyoshi, Osaka

AU - Jie, Fu

AU - Jun, Takada

AU - Yoshinari, Miura

AU - Hideki, Maekawa

PY - 1991/12

Y1 - 1991/12

N2 - New glasses were obtained in the system Al-Cd-Pb-O-F and investigated by 27Al magic angle spinning nuclear magnetic resonance spectroscopy. The chemical shift with respect to [Al(H2O)6]3+ indicated the presence of both four- and six-coordinated Al atoms (Al(4) and Al(6) units) in the glasses. Not only the fraction of Al (6) but also the number of fluorine atoms taking part in Al(6) increased with increasing fluorine content.

AB - New glasses were obtained in the system Al-Cd-Pb-O-F and investigated by 27Al magic angle spinning nuclear magnetic resonance spectroscopy. The chemical shift with respect to [Al(H2O)6]3+ indicated the presence of both four- and six-coordinated Al atoms (Al(4) and Al(6) units) in the glasses. Not only the fraction of Al (6) but also the number of fluorine atoms taking part in Al(6) increased with increasing fluorine content.

UR - http://www.scopus.com/inward/record.url?scp=0026284075&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0026284075&partnerID=8YFLogxK

U2 - 10.1016/0167-577X(91)90118-P

DO - 10.1016/0167-577X(91)90118-P

M3 - Article

AN - SCOPUS:0026284075

SN - 0167-577X

VL - 12

SP - 369

EP - 372

JO - Materials Letters

JF - Materials Letters

IS - 5

ER -

Coordination of aluminum in new glasses of the system Al-Cd-O-F

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this