@article{8aec8924b9c647b38ad606c6735461c4,
title = "Copper-catalyzed regioselective chloroamination of alkenes with chlorotrimethylsilane and n-fluorobenzenesulfonimide under microwave-assisted conditions",
abstract = "A copper-catalyzed chloroamination of alkenes with chlorotrimethylsilane and N-fluorobenzenesulfonimide has been developed. The reactions were complete within 1 h at 120 °C by means of microwave heating. The present chloroamination proceeds with a perfect regioselectivity and is compatible with various functional groups. The preliminary mechanistic investigation revealed that the reaction involves a radical process. The utility of the present method was demonstrated by scalable, operationally simple and safe system.",
keywords = "Alkenes, Chloroamination, Copper catalyst",
author = "Masayuki Iwasaki and Jie Xu and Yukari Tani and Liyan Fu and Yuichi Ikemoto and Yasuyuki Ura and Yasushi Nishihara",
note = "Funding Information: This work was partly supported by a Grant-in-Aid for Scientific Research (KAKENHI) (No. 16K17901) from JSPS. The authors gratefully thank Ms. Megumi Kosaka and Mr. Motonari Kobayashi (Department of Instrumental Analysis, Advanced Science Research Center, Okayama University) for performing elemental analyses, and the SC-NMR Laboratory (Okayama University) for the NMR spectral measurements. Publisher Copyright: {\textcopyright} 2019 The Chemical Society of Japan.",
year = "2019",
doi = "10.1246/cl.180937",
language = "English",
volume = "48",
pages = "281--284",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "3",
}