Crystal structure of (2-methyl-1-phenylsulfonyl-1H-indol-3-yl)(phenyl)methanone

M. Umadevi; V. Saravanan; R. Yamuna; A. K. Mohanakrishnanc; G. Chakkaravarthi; H. Ishida

doi:10.1107/S2056989014028059

Crystal structure of (2-methyl-1-phenylsulfonyl-1H-indol-3-yl)(phenyl)methanone

M. Umadevi, V. Saravanan, R. Yamuna, A. K. Mohanakrishnanc, G. Chakkaravarthi, H. Ishida

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, C₂₂H₁₇NO₃S, the sulfonyl-bound phenyl ring is almost orthogonal to the indole ring system, making a dihedral angle of 84.89 (7)°. The carbonyl-bound phenyl ring forms a dihedral angle of 57.32 (5)° with the indole ring system. The two phenyl rings are inclined at 52.68 (7)°. The S atom has a distorted tetrahedral configuration. In the crystal, weak C - H⋯O interactions link the molecules, forming a helical chain along the b-axis direction.

Original language	English
Pages (from-to)	133-135
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	2
DOIs	https://doi.org/10.1107/S2056989014028059
Publication status	Published - Feb 1 2015

Keywords

C - H⋯O hydrogen bonds
Crystal structure
Indole derivative

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Crystal structure of (2-methyl-1-phenylsulfonyl-1H-indol-3-yl)(phenyl)methanone",

abstract = "In the title compound, C22H17NO3S, the sulfonyl-bound phenyl ring is almost orthogonal to the indole ring system, making a dihedral angle of 84.89 (7)°. The carbonyl-bound phenyl ring forms a dihedral angle of 57.32 (5)° with the indole ring system. The two phenyl rings are inclined at 52.68 (7)°. The S atom has a distorted tetrahedral configuration. In the crystal, weak C - H⋯O interactions link the molecules, forming a helical chain along the b-axis direction.",

keywords = "C - H⋯O hydrogen bonds, Crystal structure, Indole derivative",

author = "M. Umadevi and V. Saravanan and R. Yamuna and Mohanakrishnanc, {A. K.} and G. Chakkaravarthi and H. Ishida",

year = "2015",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - Crystal structure of (2-methyl-1-phenylsulfonyl-1H-indol-3-yl)(phenyl)methanone

AU - Umadevi, M.

AU - Saravanan, V.

AU - Yamuna, R.

AU - Mohanakrishnanc, A. K.

AU - Chakkaravarthi, G.

AU - Ishida, H.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - In the title compound, C22H17NO3S, the sulfonyl-bound phenyl ring is almost orthogonal to the indole ring system, making a dihedral angle of 84.89 (7)°. The carbonyl-bound phenyl ring forms a dihedral angle of 57.32 (5)° with the indole ring system. The two phenyl rings are inclined at 52.68 (7)°. The S atom has a distorted tetrahedral configuration. In the crystal, weak C - H⋯O interactions link the molecules, forming a helical chain along the b-axis direction.

AB - In the title compound, C22H17NO3S, the sulfonyl-bound phenyl ring is almost orthogonal to the indole ring system, making a dihedral angle of 84.89 (7)°. The carbonyl-bound phenyl ring forms a dihedral angle of 57.32 (5)° with the indole ring system. The two phenyl rings are inclined at 52.68 (7)°. The S atom has a distorted tetrahedral configuration. In the crystal, weak C - H⋯O interactions link the molecules, forming a helical chain along the b-axis direction.

KW - C - H⋯O hydrogen bonds

KW - Crystal structure

KW - Indole derivative

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JO - Acta Crystallographica Section E: Structure Reports Online

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Crystal structure of (2-methyl-1-phenylsulfonyl-1H-indol-3-yl)(phenyl)methanone

Abstract

Keywords

ASJC Scopus subject areas

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