Deuterium relaxation time of α-d-tryptophan included in cyclodextrin host molecules

Iwao Tabushi; Yasuhisa Kuroda; Masahiko Yamada; Takashi Sera

doi:10.1007/BF00656341

Deuterium relaxation time of α-d-tryptophan included in cyclodextrin host molecules

Iwao Tabushi, Yasuhisa Kuroda, Masahiko Yamada, Takashi Sera

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Deuterium relaxation times of d- and l-α-d-tryptophan included in β-cyclodextrin derivatives were directly measured by deuterium NMR spectroscopy. The results showed that the molecular motion of the tryptophan molecule was strongly restricted even in the cavity of unmodified β-cyclodextrin and the additional recognition groupings - ammonium and carboxylate - on β-cyclodextrin did not affect the molecular motion of tryptophan, though the association constants were significantly enhanced.

Original language	English
Pages (from-to)	599-603
Number of pages	5
Journal	Journal of Inclusion Phenomena
Volume	6
Issue number	6
DOIs	https://doi.org/10.1007/BF00656341
Publication status	Published - Dec 1988
Externally published	Yes

Keywords

Cyclodextrin
deuterium relaxation
inclusion
receptor

ASJC Scopus subject areas

Condensed Matter Physics
Chemistry(all)

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10.1007/BF00656341

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title = "Deuterium relaxation time of α-d-tryptophan included in cyclodextrin host molecules",

abstract = "Deuterium relaxation times of d- and l-α-d-tryptophan included in β-cyclodextrin derivatives were directly measured by deuterium NMR spectroscopy. The results showed that the molecular motion of the tryptophan molecule was strongly restricted even in the cavity of unmodified β-cyclodextrin and the additional recognition groupings - ammonium and carboxylate - on β-cyclodextrin did not affect the molecular motion of tryptophan, though the association constants were significantly enhanced.",

keywords = "Cyclodextrin, deuterium relaxation, inclusion, receptor",

author = "Iwao Tabushi and Yasuhisa Kuroda and Masahiko Yamada and Takashi Sera",

year = "1988",

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doi = "10.1007/BF00656341",

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T1 - Deuterium relaxation time of α-d-tryptophan included in cyclodextrin host molecules

AU - Tabushi, Iwao

AU - Kuroda, Yasuhisa

AU - Yamada, Masahiko

AU - Sera, Takashi

PY - 1988/12

Y1 - 1988/12

N2 - Deuterium relaxation times of d- and l-α-d-tryptophan included in β-cyclodextrin derivatives were directly measured by deuterium NMR spectroscopy. The results showed that the molecular motion of the tryptophan molecule was strongly restricted even in the cavity of unmodified β-cyclodextrin and the additional recognition groupings - ammonium and carboxylate - on β-cyclodextrin did not affect the molecular motion of tryptophan, though the association constants were significantly enhanced.

AB - Deuterium relaxation times of d- and l-α-d-tryptophan included in β-cyclodextrin derivatives were directly measured by deuterium NMR spectroscopy. The results showed that the molecular motion of the tryptophan molecule was strongly restricted even in the cavity of unmodified β-cyclodextrin and the additional recognition groupings - ammonium and carboxylate - on β-cyclodextrin did not affect the molecular motion of tryptophan, though the association constants were significantly enhanced.

KW - Cyclodextrin

KW - deuterium relaxation

KW - inclusion

KW - receptor

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JF - Journal of Inclusion Phenomena

IS - 6

ER -

Deuterium relaxation time of α-d-tryptophan included in cyclodextrin host molecules

Abstract

Keywords

ASJC Scopus subject areas

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