Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility

Koichi Mitsudo; Haruka Inoue; Yuta Niki; Eisuke Sato; Seiji Suga

doi:10.3762/bjoc.18.107

Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility

Koichi Mitsudo, Haruka Inoue, Yuta Niki, Eisuke Sato, Seiji Suga

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).

Original language	English
Pages (from-to)	1055-1061
Number of pages	7
Journal	Beilstein Journal of Organic Chemistry
Volume	18
DOIs	https://doi.org/10.3762/bjoc.18.107
Publication status	Published - 2022

Keywords

enone
hydrogenation
iridium
palladium
PEM reactor

ASJC Scopus subject areas

Organic Chemistry

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10.3762/bjoc.18.107

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title = "Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility",

abstract = "Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).",

keywords = "enone, hydrogenation, iridium, palladium, PEM reactor",

author = "Koichi Mitsudo and Haruka Inoue and Yuta Niki and Eisuke Sato and Seiji Suga",

note = "Funding Information: This work was supported in part by JST CREST Grant No. JP65R1204400, Japan, JSPS KAKENHI Grant Number JP19K05477, JP19K05478, and JP22H02122. Publisher Copyright: {\textcopyright} 2022 Mitsudo et al.; licensee Beilstein-Institut.",

year = "2022",

doi = "10.3762/bjoc.18.107",

language = "English",

volume = "18",

pages = "1055--1061",

journal = "Beilstein Journal of Organic Chemistry",

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TY - JOUR

T1 - Electrochemical hydrogenation of enones using a proton-exchange membrane reactor

T2 - selectivity and utility

AU - Mitsudo, Koichi

AU - Inoue, Haruka

AU - Niki, Yuta

AU - Sato, Eisuke

AU - Suga, Seiji

N1 - Funding Information: This work was supported in part by JST CREST Grant No. JP65R1204400, Japan, JSPS KAKENHI Grant Number JP19K05477, JP19K05478, and JP22H02122. Publisher Copyright: © 2022 Mitsudo et al.; licensee Beilstein-Institut.

PY - 2022

Y1 - 2022

N2 - Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).

AB - Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).

KW - enone

KW - hydrogenation

KW - iridium

KW - palladium

KW - PEM reactor

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DO - 10.3762/bjoc.18.107

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VL - 18

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EP - 1061

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

ER -

Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility

Abstract

Keywords

ASJC Scopus subject areas

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