Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y2c2@c82: Ultraviolet photoelectron spectroscopy and theoretical calculation

Shojun Hino; Takafumi Miyazaki; Yusuke Aoki; Norihiko Wanita; Masayuki Kato; Ryohei Sumii; Takao Akachi; Takeshi Inoue; Yasuhiro Ito; Toshiki Sugai; Hisanori Shinohara

doi:10.1246/bcsj.82.963

Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y₂c₂@c₈₂: Ultraviolet photoelectron spectroscopy and theoretical calculation

Shojun Hino, Takafumi Miyazaki, Yusuke Aoki, Norihiko Wanita, Masayuki Kato, Ryohei Sumii, Takao Akachi, Takeshi Inoue, Yasuhiro Ito, Toshiki Sugai, Hisanori Shinohara

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Ultraviolet photoelectron spectra (UPS) of two yttrium atoms and two carbon atoms encapsulated metallofullerenes, Y₂C₂@C₈₂ were measured using a synchrotron radiation light source. Their upper valence band UPS differ significantly from each other, while the lower valence band ones are almost the same. The UPS of Y₂C₂@C₈₂ (II) couldbe well reproduced by simulated spectra obtained with a Gaussian 03 program module assuming a distorted Y₂C₂ tetragonalform in C _2v C₈₂ cage structure.

Original language	English
Pages (from-to)	963-967
Number of pages	5
Journal	Bulletin of the Chemical Society of Japan
Volume	82
Issue number	8
DOIs	https://doi.org/10.1246/bcsj.82.963
Publication status	Published - Aug 25 2009
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/bcsj.82.963

Cite this

Hino, S., Miyazaki, T., Aoki, Y., Wanita, N., Kato, M., Sumii, R., Akachi, T., Inoue, T., Ito, Y., Sugai, T., & Shinohara, H. (2009). Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y₂c₂@c₈₂: Ultraviolet photoelectron spectroscopy and theoretical calculation. Bulletin of the Chemical Society of Japan, 82(8), 963-967. https://doi.org/10.1246/bcsj.82.963

Hino, S, Miyazaki, T, Aoki, Y, Wanita, N, Kato, M, Sumii, R, Akachi, T, Inoue, T, Ito, Y, Sugai, T & Shinohara, H 2009, 'Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y₂c₂@c₈₂: Ultraviolet photoelectron spectroscopy and theoretical calculation', Bulletin of the Chemical Society of Japan, vol. 82, no. 8, pp. 963-967. https://doi.org/10.1246/bcsj.82.963

@article{c0ca0a957bd84c8d8ffa66d335a3597e,

title = "Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y2c2@c82: Ultraviolet photoelectron spectroscopy and theoretical calculation",

abstract = "Ultraviolet photoelectron spectra (UPS) of two yttrium atoms and two carbon atoms encapsulated metallofullerenes, Y2C2@C82 were measured using a synchrotron radiation light source. Their upper valence band UPS differ significantly from each other, while the lower valence band ones are almost the same. The UPS of Y2C2@C82 (II) couldbe well reproduced by simulated spectra obtained with a Gaussian 03 program module assuming a distorted Y2C2 tetragonalform in C 2v C82 cage structure.",

author = "Shojun Hino and Takafumi Miyazaki and Yusuke Aoki and Norihiko Wanita and Masayuki Kato and Ryohei Sumii and Takao Akachi and Takeshi Inoue and Yasuhiro Ito and Toshiki Sugai and Hisanori Shinohara",

year = "2009",

month = aug,

day = "25",

doi = "10.1246/bcsj.82.963",

language = "English",

volume = "82",

pages = "963--967",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Chemical Society of Japan",

number = "8",

}

TY - JOUR

T1 - Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y2c2@c82

T2 - Ultraviolet photoelectron spectroscopy and theoretical calculation

AU - Hino, Shojun

AU - Miyazaki, Takafumi

AU - Aoki, Yusuke

AU - Wanita, Norihiko

AU - Kato, Masayuki

AU - Sumii, Ryohei

AU - Akachi, Takao

AU - Inoue, Takeshi

AU - Ito, Yasuhiro

AU - Sugai, Toshiki

AU - Shinohara, Hisanori

PY - 2009/8/25

Y1 - 2009/8/25

N2 - Ultraviolet photoelectron spectra (UPS) of two yttrium atoms and two carbon atoms encapsulated metallofullerenes, Y2C2@C82 were measured using a synchrotron radiation light source. Their upper valence band UPS differ significantly from each other, while the lower valence band ones are almost the same. The UPS of Y2C2@C82 (II) couldbe well reproduced by simulated spectra obtained with a Gaussian 03 program module assuming a distorted Y2C2 tetragonalform in C 2v C82 cage structure.

AB - Ultraviolet photoelectron spectra (UPS) of two yttrium atoms and two carbon atoms encapsulated metallofullerenes, Y2C2@C82 were measured using a synchrotron radiation light source. Their upper valence band UPS differ significantly from each other, while the lower valence band ones are almost the same. The UPS of Y2C2@C82 (II) couldbe well reproduced by simulated spectra obtained with a Gaussian 03 program module assuming a distorted Y2C2 tetragonalform in C 2v C82 cage structure.

UR - http://www.scopus.com/inward/record.url?scp=68949175154&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=68949175154&partnerID=8YFLogxK

U2 - 10.1246/bcsj.82.963

DO - 10.1246/bcsj.82.963

M3 - Article

AN - SCOPUS:68949175154

SN - 0009-2673

VL - 82

SP - 963

EP - 967

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 8

ER -

Electronic structure of yttrium and carbon atoms encapsulated metallofullerenes, y₂c₂@c₈₂: Ultraviolet photoelectron spectroscopy and theoretical calculation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this