Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system: Approach to totally closed system

Manabu Kuroboshi; Kentaro Goto; Hideo Tanaka

doi:10.1055/s-0028-1087987

Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system: Approach to totally closed system

Manabu Kuroboshi, Kentaro Goto, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO₃ solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

Original language	English
Article number	F20808SS
Pages (from-to)	903-908
Number of pages	6
Journal	Synthesis
Issue number	6
DOIs	https://doi.org/10.1055/s-0028-1087987
Publication status	Published - Mar 2009

Keywords

Alcohols
Electron transfer
Oxidations
Solid-phase synthesis

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-0028-1087987

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abstract = "Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.",

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author = "Manabu Kuroboshi and Kentaro Goto and Hideo Tanaka",

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T2 - Approach to totally closed system

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AU - Goto, Kentaro

AU - Tanaka, Hideo

PY - 2009/3

Y1 - 2009/3

N2 - Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

AB - Electrooxidation of alcohols in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and an aqueous NaBr/NaHCO3 solution as a disperse medium proceeded smoothly to give the corresponding carbonyl compounds. The N-oxyl-immobilized silica gel 1 was prepared by silane-coupling method. Recycling of both the aqueous solution and the N-oxyl-immobilized silica gel 1 was performed successfully.

KW - Alcohols

KW - Electron transfer

KW - Oxidations

KW - Solid-phase synthesis

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Electrooxidation of alcohols in N-oxyl-immobilized silica gel/water disperse system: Approach to totally closed system

Abstract

Keywords

ASJC Scopus subject areas

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