Electroreductive "Barbier Type" allylation of imines with a combination of a Pb(0)/Pb(II) redox mediator and sacrificial anode (Al)

Hideo Tanaka; Takao Nakahara; Hamid Dhimane; Sigeru Torii

doi:10.1016/S0040-4039(00)99348-1

Electroreductive "Barbier Type" allylation of imines with a combination of a Pb(0)/Pb(II) redox mediator and sacrificial anode (Al)

Hideo Tanaka, Takao Nakahara, Hamid Dhimane, Sigeru Torii

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

An electroreductive "Barbier Type" allylation of imines with allyl bromide has been performed in a PbBr₂/Bu₄NBr/THF-(Al anode)-(Pt cathode) system. A combination of Pb(0)/Pb(II) redox and a sacrificial aluminum anode works as a mediator for both cathodic and anodic electron transfer processes, respectively.

Original language	English
Pages (from-to)	4161-4164
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(00)99348-1
Publication status	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Electroreductive {"}Barbier Type{"} allylation of imines with a combination of a Pb(0)/Pb(II) redox mediator and sacrificial anode (Al)",

abstract = "An electroreductive {"}Barbier Type{"} allylation of imines with allyl bromide has been performed in a PbBr2/Bu4NBr/THF-(Al anode)-(Pt cathode) system. A combination of Pb(0)/Pb(II) redox and a sacrificial aluminum anode works as a mediator for both cathodic and anodic electron transfer processes, respectively.",

author = "Hideo Tanaka and Takao Nakahara and Hamid Dhimane and Sigeru Torii",

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T1 - Electroreductive "Barbier Type" allylation of imines with a combination of a Pb(0)/Pb(II) redox mediator and sacrificial anode (Al)

AU - Tanaka, Hideo

AU - Nakahara, Takao

AU - Dhimane, Hamid

AU - Torii, Sigeru

PY - 1989

Y1 - 1989

N2 - An electroreductive "Barbier Type" allylation of imines with allyl bromide has been performed in a PbBr2/Bu4NBr/THF-(Al anode)-(Pt cathode) system. A combination of Pb(0)/Pb(II) redox and a sacrificial aluminum anode works as a mediator for both cathodic and anodic electron transfer processes, respectively.

AB - An electroreductive "Barbier Type" allylation of imines with allyl bromide has been performed in a PbBr2/Bu4NBr/THF-(Al anode)-(Pt cathode) system. A combination of Pb(0)/Pb(II) redox and a sacrificial aluminum anode works as a mediator for both cathodic and anodic electron transfer processes, respectively.

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U2 - 10.1016/S0040-4039(00)99348-1

DO - 10.1016/S0040-4039(00)99348-1

M3 - Article

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ER -

Electroreductive "Barbier Type" allylation of imines with a combination of a Pb(0)/Pb(II) redox mediator and sacrificial anode (Al)

Abstract

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