Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Hiromasa Kiyota; Daisuke Nakashima; Shigefumi Kuwahara; Takayuki Oritani

doi:10.1515/znb-2008-1217

Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Hiromasa Kiyota
, Daisuke Nakashima
, Shigefumi Kuwahara
, Takayuki Oritani

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

Original language	English
Pages (from-to)	1441-1442
Number of pages	2
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	63
Issue number	12
DOIs	https://doi.org/10.1515/znb-2008-1217
Publication status	Published - 2008
Externally published	Yes

Keywords

Bicyclo[2.2.1 ]heptan-2-ol
Chloroacetate
Enzymatic resolution
Lipases
Transesterification

ASJC Scopus subject areas

General Chemistry

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@article{00d359d0aad54cc09e31449057ab2648,

title = "Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids",

abstract = "Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.",

keywords = "Bicyclo[2.2.1 ]heptan-2-ol, Chloroacetate, Enzymatic resolution, Lipases, Transesterification",

author = "Hiromasa Kiyota and Daisuke Nakashima and Shigefumi Kuwahara and Takayuki Oritani",

note = "Funding Information: We thank Roche Diagnostics K. K. for the gifts of various lipases. This work was partially supported by a Grant-in-aid for Scientific Research from the Japan Society for the Promotion of Science (19580120).",

year = "2008",

doi = "10.1515/znb-2008-1217",

language = "English",

volume = "63",

pages = "1441--1442",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "12",

}

TY - JOUR

T1 - Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

AU - Kiyota, Hiromasa

AU - Nakashima, Daisuke

AU - Kuwahara, Shigefumi

AU - Oritani, Takayuki

N1 - Funding Information: We thank Roche Diagnostics K. K. for the gifts of various lipases. This work was partially supported by a Grant-in-aid for Scientific Research from the Japan Society for the Promotion of Science (19580120).

PY - 2008

Y1 - 2008

N2 - Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

AB - Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

KW - Bicyclo[2.2.1 ]heptan-2-ol

KW - Chloroacetate

KW - Enzymatic resolution

KW - Lipases

KW - Transesterification

UR - https://www.scopus.com/pages/publications/58049154646

UR - https://www.scopus.com/pages/publications/58049154646#tab=citedBy

U2 - 10.1515/znb-2008-1217

DO - 10.1515/znb-2008-1217

M3 - Article

AN - SCOPUS:58049154646

SN - 0932-0776

VL - 63

SP - 1441

EP - 1442

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 12

ER -

Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Abstract

Keywords

ASJC Scopus subject areas

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