TY - JOUR
T1 - EPR studies at high-pressure. VI. Spin-exchange reaction of nitroxide radical with copper(II) and iron(III) complexes
AU - Sueishi, Yoshimi
AU - Hori, Arimitsu
PY - 2001/12/1
Y1 - 2001/12/1
N2 - The spin exchange of nitroxide with copper(II) and iron(III) complexes was studied by means of a high-pressure EPR technique. The spin exchange with CuII complexes exhibited the aspect of weak exchange, independent of the kinds of coordinated ligands, while the spin exchange with FeIII complexes was found to vary from weak exchange to a strong one, dependent of the solvent viscosity. Based on the results, the spin exchange with CuII and FeIII complexes is discussed in detail.
AB - The spin exchange of nitroxide with copper(II) and iron(III) complexes was studied by means of a high-pressure EPR technique. The spin exchange with CuII complexes exhibited the aspect of weak exchange, independent of the kinds of coordinated ligands, while the spin exchange with FeIII complexes was found to vary from weak exchange to a strong one, dependent of the solvent viscosity. Based on the results, the spin exchange with CuII and FeIII complexes is discussed in detail.
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U2 - 10.1246/bcsj.74.2431
DO - 10.1246/bcsj.74.2431
M3 - Article
AN - SCOPUS:0035688506
SN - 0009-2673
VL - 74
SP - 2431
EP - 2432
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 12
ER -