Fabrication of ring oscillators using organic molecules of phenacene and perylenedicarboximide

Organic field-effect transistors (FETs) can be applied to radio-frequency identification tags (RFIDs) and active-matrix flat-panel displays. For RFID application, a cardinal functional block is a ring oscillator using an odd number of inverters to convert DC voltage to AC. Herein, we report the properties of two ring oscillators, one formed with [6]phenacene for a p-channel FET andN,N′-dioctyl-3,4,9,10-perylenedicarboximide (PTCDI-C8) for an n-channel FET, and one formed with 3,10-ditetradecylpicene ((C₁₄H₂₉)₂-picene) for a p-channel FET and PTCDI-C8 for an n-channel FET. The former ring oscillator provided a maximum oscillation frequency,f_oscof 26 Hz, and the latter a maximumf_oscof 21 Hz. The drain-drain voltage,V_DD, applied to these ring oscillators was 100 V. This may be the first step towards a future practical ring oscillator using phenacene molecules. The values of field-effect mobility,μin the p-channel [6]phenacene FET and n-channel PTCDI-C8 FET, which form the building blocks in the ring oscillator with anf_oscvalue of 26 Hz, are 1.19 and 1.50 × 10⁻¹cm²V⁻¹s⁻¹, respectively, while the values in the p-channel (C₁₄H₂₉)₂-picene FET and n-channel PTCDI-C8 FET, which form the ring oscillator with anf_oscof 21 Hz, are 1.85 and 1.54 × 10⁻¹cm²V⁻¹s⁻¹, respectively. Theμvalues in the p-channel FETs are higher by one order of magnitude than those of the n-channel FET, which must be addressed to increase the value off_osc. Finally, we fabricated a ring oscillator with ZrO₂instead of parylene for the gate dielectric, which provided the low-voltage operation of the ring oscillator, in which [6]phenacene and PTCDI-C8 thin-film FETs were employed. The value off_oscobtained in the ring oscillator was 24 Hz. In this ring oscillator, theV_DDvalue applied was limited to 20 V. The durability of the ring oscillators was also investigated, and the bias stress effect on thef_oscand the amplitude of the output voltage,V_outare discussed. This successful operation of ring oscillators represents an important step towards the realization of future practical integrated logic gate circuits using phenacene molecules.