Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides

Yoshiji Okada; Manabu Kuroboshi; Takashi Ishihara

doi:10.1016/S0022-1139(00)81045-3

Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides

Yoshiji Okada, Manabu Kuroboshi, Takashi Ishihara

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

1-Substituted F-1-alkenyl phosphates, easily prepared from F-alkyl ketones and the sodium salt of diethyl phosphite, were allowed to react with various phosphonium ylides in tetrahydrofuran or hexane at room temperature or at the reflux temperature of the solvent to lead to the corresponding polyfluorinated 1,3-diene derivatives in moderate to good yields.

Original language	English
Pages (from-to)	435-438
Number of pages	4
Journal	Journal of Fluorine Chemistry
Volume	41
Issue number	3
DOIs	https://doi.org/10.1016/S0022-1139(00)81045-3
Publication status	Published - Dec 1988
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Environmental Chemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1016/S0022-1139(00)81045-3

Cite this

@article{317aa844ed994b79b13989d42ca6df3d,

title = "Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides",

abstract = "1-Substituted F-1-alkenyl phosphates, easily prepared from F-alkyl ketones and the sodium salt of diethyl phosphite, were allowed to react with various phosphonium ylides in tetrahydrofuran or hexane at room temperature or at the reflux temperature of the solvent to lead to the corresponding polyfluorinated 1,3-diene derivatives in moderate to good yields.",

author = "Yoshiji Okada and Manabu Kuroboshi and Takashi Ishihara",

year = "1988",

month = dec,

doi = "10.1016/S0022-1139(00)81045-3",

language = "English",

volume = "41",

pages = "435--438",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier BV",

number = "3",

}

TY - JOUR

T1 - Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides

AU - Okada, Yoshiji

AU - Kuroboshi, Manabu

AU - Ishihara, Takashi

PY - 1988/12

Y1 - 1988/12

N2 - 1-Substituted F-1-alkenyl phosphates, easily prepared from F-alkyl ketones and the sodium salt of diethyl phosphite, were allowed to react with various phosphonium ylides in tetrahydrofuran or hexane at room temperature or at the reflux temperature of the solvent to lead to the corresponding polyfluorinated 1,3-diene derivatives in moderate to good yields.

AB - 1-Substituted F-1-alkenyl phosphates, easily prepared from F-alkyl ketones and the sodium salt of diethyl phosphite, were allowed to react with various phosphonium ylides in tetrahydrofuran or hexane at room temperature or at the reflux temperature of the solvent to lead to the corresponding polyfluorinated 1,3-diene derivatives in moderate to good yields.

UR - http://www.scopus.com/inward/record.url?scp=36749012810&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=36749012810&partnerID=8YFLogxK

U2 - 10.1016/S0022-1139(00)81045-3

DO - 10.1016/S0022-1139(00)81045-3

M3 - Article

AN - SCOPUS:36749012810

SN - 0022-1139

VL - 41

SP - 435

EP - 438

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 3

ER -

Facile transformation of 1-substituted F-1-alkenyl phosphates into polyfluorinated 1,3-dienes by use of phosphonium ylides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this