Fluoride Complexation of Element 104, Rutherfordium

Hiromitsu Haba; Kazuaki Tsukada; Masato Asai; Atsushi Toyoshima; Kazuhiko Akiyama; Ichiro Nishinaka; Masaru Hirata; Tsuyoshi Yaita; Shin Ichi Ichikawa; Yuichiro Nagame; Ken Ichiro Yasuda; Yutaka Miyamoto; Tetsuya Kaneko; Shin Ichi Goto; Sawako Ono; Toshiyuki Hirai; Hisaaki Kudo; Mitsuru Shigekawa; Atsushi Shinohara; Yasuji Oura; Hiromichi Nakahara; Keisuke Sueki; Hidetoshi Kikunaga; Norikazu Kinoshita; Naoya Tsuruga; Akihiko Yokoyama; Minoru Sakama; Shuich Enomoto; Matthias Schädel; Willy Brüchle; Jens V. Kratz

doi:10.1021/ja031824u

Fluoride Complexation of Element 104, Rutherfordium

Hiromitsu Haba, Kazuaki Tsukada, Masato Asai, Atsushi Toyoshima, Kazuhiko Akiyama, Ichiro Nishinaka, Masaru Hirata, Tsuyoshi Yaita, Shin Ichi Ichikawa, Yuichiro Nagame, Ken Ichiro Yasuda, Yutaka Miyamoto, Tetsuya Kaneko, Shin Ichi Goto, Sawako Ono, Toshiyuki Hirai, Hisaaki Kudo, Mitsuru Shigekawa, Atsushi Shinohara, Yasuji OuraHiromichi Nakahara, Keisuke Sueki, Hidetoshi Kikunaga, Norikazu Kinoshita, Naoya Tsuruga, Akihiko Yokoyama, Minoru Sakama, Shuich Enomoto, Matthias Schädel, Willy Brüchle, Jens V. Kratz

Faculty of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Fluoride complexation of element 104, rutherfordium (Rf), produced in the ²⁴⁸Cm(¹⁸O,5n)²⁶¹ Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the ¹⁸O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

Original language	English
Pages (from-to)	5219-5224
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	126
Issue number	16
DOIs	https://doi.org/10.1021/ja031824u
Publication status	Published - Apr 28 2004

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Haba, H., Tsukada, K., Asai, M., Toyoshima, A., Akiyama, K., Nishinaka, I., Hirata, M., Yaita, T., Ichikawa, S. I., Nagame, Y., Yasuda, K. I., Miyamoto, Y., Kaneko, T., Goto, S. I., Ono, S., Hirai, T., Kudo, H., Shigekawa, M., Shinohara, A., ... Kratz, J. V. (2004). Fluoride Complexation of Element 104, Rutherfordium. Journal of the American Chemical Society, 126(16), 5219-5224. https://doi.org/10.1021/ja031824u

Haba, H, Tsukada, K, Asai, M, Toyoshima, A, Akiyama, K, Nishinaka, I, Hirata, M, Yaita, T, Ichikawa, SI, Nagame, Y, Yasuda, KI, Miyamoto, Y, Kaneko, T, Goto, SI, Ono, S, Hirai, T, Kudo, H, Shigekawa, M, Shinohara, A, Oura, Y, Nakahara, H, Sueki, K, Kikunaga, H, Kinoshita, N, Tsuruga, N, Yokoyama, A, Sakama, M, Enomoto, S, Schädel, M, Brüchle, W & Kratz, JV 2004, 'Fluoride Complexation of Element 104, Rutherfordium', Journal of the American Chemical Society, vol. 126, no. 16, pp. 5219-5224. https://doi.org/10.1021/ja031824u

@article{fafae4139a5a490dbaa7556666e35a7b,

title = "Fluoride Complexation of Element 104, Rutherfordium",

abstract = "Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261 Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.",

author = "Hiromitsu Haba and Kazuaki Tsukada and Masato Asai and Atsushi Toyoshima and Kazuhiko Akiyama and Ichiro Nishinaka and Masaru Hirata and Tsuyoshi Yaita and Ichikawa, {Shin Ichi} and Yuichiro Nagame and Yasuda, {Ken Ichiro} and Yutaka Miyamoto and Tetsuya Kaneko and Goto, {Shin Ichi} and Sawako Ono and Toshiyuki Hirai and Hisaaki Kudo and Mitsuru Shigekawa and Atsushi Shinohara and Yasuji Oura and Hiromichi Nakahara and Keisuke Sueki and Hidetoshi Kikunaga and Norikazu Kinoshita and Naoya Tsuruga and Akihiko Yokoyama and Minoru Sakama and Shuich Enomoto and Matthias Sch{\"a}del and Willy Br{\"u}chle and Kratz, {Jens V.}",

year = "2004",

month = apr,

day = "28",

doi = "10.1021/ja031824u",

language = "English",

volume = "126",

pages = "5219--5224",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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T1 - Fluoride Complexation of Element 104, Rutherfordium

AU - Haba, Hiromitsu

AU - Tsukada, Kazuaki

AU - Asai, Masato

AU - Toyoshima, Atsushi

AU - Akiyama, Kazuhiko

AU - Nishinaka, Ichiro

AU - Hirata, Masaru

AU - Yaita, Tsuyoshi

AU - Ichikawa, Shin Ichi

AU - Nagame, Yuichiro

AU - Yasuda, Ken Ichiro

AU - Miyamoto, Yutaka

AU - Kaneko, Tetsuya

AU - Goto, Shin Ichi

AU - Ono, Sawako

AU - Hirai, Toshiyuki

AU - Kudo, Hisaaki

AU - Shigekawa, Mitsuru

AU - Shinohara, Atsushi

AU - Oura, Yasuji

AU - Nakahara, Hiromichi

AU - Sueki, Keisuke

AU - Kikunaga, Hidetoshi

AU - Kinoshita, Norikazu

AU - Tsuruga, Naoya

AU - Yokoyama, Akihiko

AU - Sakama, Minoru

AU - Enomoto, Shuich

AU - Schädel, Matthias

AU - Brüchle, Willy

AU - Kratz, Jens V.

PY - 2004/4/28

Y1 - 2004/4/28

N2 - Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261 Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

AB - Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261 Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

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EP - 5224

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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Fluoride Complexation of Element 104, Rutherfordium

Abstract

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