Abstract
Volatilization and mass fractionation of boron during evaporation of the hydrofluoric and hydrochloric acid solutions were investigated with varying mannitol/boron ratios. The degree of volatilization and mass fractionation decreases with increasing mannitol/boron mol ratio and the boron volatilization is completely suppressed when the ratio is more than unity. These results indicate that the final stable compound of boron-mannitol complex is an equimolar complex of boron and mannitol. The formation of this complex allows the use of hydrofluoric and hydrochloric acids for the dissolution of silicate rock samples and for separation of boron from the samples adopting anion exchange chromatography in F~ form.
| Original language | English |
|---|---|
| Pages (from-to) | 91-95 |
| Number of pages | 5 |
| Journal | Proceedings of the Japan Academy, Series B |
| Volume | 66 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 1990 |
Keywords
- Boron-mannitol complex
- boron isotopic composition
- mass fractionation
ASJC Scopus subject areas
- Agricultural and Biological Sciences(all)
- Physics and Astronomy(all)