Generation and Carbonyl Addition of Dibromofluoromethyllithium

Manabu Kuroboshi; Nobuko Yamada; Yoko Takebe; Tamejiro Hiyama

doi:10.1055/s-1995-5145

Generation and Carbonyl Addition of Dibromofluoromethyllithium

Manabu Kuroboshi, Nobuko Yamada, Yoko Takebe, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

When CFBr₃ was treated with n-BuLi at -130 °C, thermally labile LiCFBr₂ was generated which reacted smoothly with a coexisting electrophile RR'CO to give an adduct RR'C(OH)CFBr₂ in good yield.

Original language	English
Pages (from-to)	987-988
Number of pages	2
Journal	Synlett
Volume	1995
Issue number	9
DOIs	https://doi.org/10.1055/s-1995-5145
Publication status	Published - Sept 1995

Keywords

carbenoid
carbonyl addition
fluorinated alcohol
halofluoromethane
halohydrin

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1995-5145

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title = "Generation and Carbonyl Addition of Dibromofluoromethyllithium",

abstract = "When CFBr3 was treated with n-BuLi at -130 °C, thermally labile LiCFBr2 was generated which reacted smoothly with a coexisting electrophile RR'CO to give an adduct RR'C(OH)CFBr2 in good yield.",

keywords = "carbenoid, carbonyl addition, fluorinated alcohol, halofluoromethane, halohydrin",

author = "Manabu Kuroboshi and Nobuko Yamada and Yoko Takebe and Tamejiro Hiyama",

year = "1995",

month = sep,

doi = "10.1055/s-1995-5145",

language = "English",

volume = "1995",

pages = "987--988",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "9",

}

TY - JOUR

T1 - Generation and Carbonyl Addition of Dibromofluoromethyllithium

AU - Kuroboshi, Manabu

AU - Yamada, Nobuko

AU - Takebe, Yoko

AU - Hiyama, Tamejiro

PY - 1995/9

Y1 - 1995/9

N2 - When CFBr3 was treated with n-BuLi at -130 °C, thermally labile LiCFBr2 was generated which reacted smoothly with a coexisting electrophile RR'CO to give an adduct RR'C(OH)CFBr2 in good yield.

AB - When CFBr3 was treated with n-BuLi at -130 °C, thermally labile LiCFBr2 was generated which reacted smoothly with a coexisting electrophile RR'CO to give an adduct RR'C(OH)CFBr2 in good yield.

KW - carbenoid

KW - carbonyl addition

KW - fluorinated alcohol

KW - halofluoromethane

KW - halohydrin

UR - http://www.scopus.com/inward/record.url?scp=0011843191&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0011843191&partnerID=8YFLogxK

U2 - 10.1055/s-1995-5145

DO - 10.1055/s-1995-5145

M3 - Article

AN - SCOPUS:0011843191

SN - 0936-5214

VL - 1995

SP - 987

EP - 988

JO - Synlett

JF - Synlett

IS - 9

ER -

Generation and Carbonyl Addition of Dibromofluoromethyllithium

Abstract

Keywords

ASJC Scopus subject areas

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