Geometric selectivity, hydrogen-bonding interaction, and solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)

Ryoji Mitsuhashi; Takayoshi Suzuki; Yukinari Sunatsuki; Masaaki Kojima

doi:10.1246/cl.2011.696

Geometric selectivity, hydrogen-bonding interaction, and solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)

Ryoji Mitsuhashi, Takayoshi Suzuki, Yukinari Sunatsuki, Masaaki Kojima

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3 Citations (Scopus)

Abstract

Cobalt(III) complexes with N-(aminoalkyl)salicylamide dianions, Ln ^2- (n = 14), have been prepared and their molecular and crystal structures have been determined. The geometric (mer- or fac-) selectivity of [Co(Ln)₂]^- complexes was dependent on the number of the amineamidato chelate ring member. Intermolecular homochiral hydrogen-bonds and solvatochromic behavior of the complexes were also observed.

Original language	English
Pages (from-to)	696-698
Number of pages	3
Journal	Chemistry Letters
Volume	40
Issue number	7
DOIs	https://doi.org/10.1246/cl.2011.696
Publication status	Published - 2011

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2011.696

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title = "Geometric selectivity, hydrogen-bonding interaction, and solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)",

abstract = "Cobalt(III) complexes with N-(aminoalkyl)salicylamide dianions, Ln 2- (n = 14), have been prepared and their molecular and crystal structures have been determined. The geometric (mer- or fac-) selectivity of [Co(Ln)2]- complexes was dependent on the number of the amineamidato chelate ring member. Intermolecular homochiral hydrogen-bonds and solvatochromic behavior of the complexes were also observed.",

author = "Ryoji Mitsuhashi and Takayoshi Suzuki and Yukinari Sunatsuki and Masaaki Kojima",

year = "2011",

doi = "10.1246/cl.2011.696",

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pages = "696--698",

journal = "Chemistry Letters",

issn = "0366-7022",

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T1 - Geometric selectivity, hydrogen-bonding interaction, and solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)

AU - Mitsuhashi, Ryoji

AU - Suzuki, Takayoshi

AU - Sunatsuki, Yukinari

AU - Kojima, Masaaki

PY - 2011

Y1 - 2011

N2 - Cobalt(III) complexes with N-(aminoalkyl)salicylamide dianions, Ln 2- (n = 14), have been prepared and their molecular and crystal structures have been determined. The geometric (mer- or fac-) selectivity of [Co(Ln)2]- complexes was dependent on the number of the amineamidato chelate ring member. Intermolecular homochiral hydrogen-bonds and solvatochromic behavior of the complexes were also observed.

AB - Cobalt(III) complexes with N-(aminoalkyl)salicylamide dianions, Ln 2- (n = 14), have been prepared and their molecular and crystal structures have been determined. The geometric (mer- or fac-) selectivity of [Co(Ln)2]- complexes was dependent on the number of the amineamidato chelate ring member. Intermolecular homochiral hydrogen-bonds and solvatochromic behavior of the complexes were also observed.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

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Geometric selectivity, hydrogen-bonding interaction, and solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)

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