Homo-coupling polycondensation of bis(alkynylsilane)s mediated by copper(I) chloride: A new synthesis of poly(arylenebutadiynylene)s

Yasushi Nishihara; Tsuyoshi Kato; Jun ichi Ando; Atsunori Mori; Tamejiro Hiyama

doi:10.1246/cl.2001.950

Homo-coupling polycondensation of bis(alkynylsilane)s mediated by copper(I) chloride: A new synthesis of poly(arylenebutadiynylene)s

Yasushi Nishihara, Tsuyoshi Kato, Jun ichi Ando, Atsunori Mori, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Homo-coupling polycondensation of aromatic compounds bearing two (trimethylsilyl)ethynyl groups mediated by copper(I) chloride in DMF gives conjugated poly(arylenebutadiynylene)s in up to 94% yield with molecular weight of 4000-8900 (M_w/M_n = 1.78-2.09).

Original language	English
Pages (from-to)	950-951
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.2001.950
Publication status	Published - 2001
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2001.950

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title = "Homo-coupling polycondensation of bis(alkynylsilane)s mediated by copper(I) chloride: A new synthesis of poly(arylenebutadiynylene)s",

abstract = "Homo-coupling polycondensation of aromatic compounds bearing two (trimethylsilyl)ethynyl groups mediated by copper(I) chloride in DMF gives conjugated poly(arylenebutadiynylene)s in up to 94% yield with molecular weight of 4000-8900 (Mw/Mn = 1.78-2.09).",

author = "Yasushi Nishihara and Tsuyoshi Kato and Ando, {Jun ichi} and Atsunori Mori and Tamejiro Hiyama",

year = "2001",

doi = "10.1246/cl.2001.950",

language = "English",

pages = "950--951",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

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T1 - Homo-coupling polycondensation of bis(alkynylsilane)s mediated by copper(I) chloride

T2 - A new synthesis of poly(arylenebutadiynylene)s

AU - Nishihara, Yasushi

AU - Kato, Tsuyoshi

AU - Ando, Jun ichi

AU - Mori, Atsunori

AU - Hiyama, Tamejiro

PY - 2001

Y1 - 2001

N2 - Homo-coupling polycondensation of aromatic compounds bearing two (trimethylsilyl)ethynyl groups mediated by copper(I) chloride in DMF gives conjugated poly(arylenebutadiynylene)s in up to 94% yield with molecular weight of 4000-8900 (Mw/Mn = 1.78-2.09).

AB - Homo-coupling polycondensation of aromatic compounds bearing two (trimethylsilyl)ethynyl groups mediated by copper(I) chloride in DMF gives conjugated poly(arylenebutadiynylene)s in up to 94% yield with molecular weight of 4000-8900 (Mw/Mn = 1.78-2.09).

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U2 - 10.1246/cl.2001.950

DO - 10.1246/cl.2001.950

M3 - Article

AN - SCOPUS:0035541241

SN - 0366-7022

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Homo-coupling polycondensation of bis(alkynylsilane)s mediated by copper(I) chloride: A new synthesis of poly(arylenebutadiynylene)s

Abstract

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