Hybridization effects and multipole orders in Pr skutterudites

Yoshio Kuramoto, Junya Otsuki, Annamária Kiss, Hiroaki Kusunose

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14 Citations (Scopus)


Theoretical account is given of 4f-electron dynamics and multipole orders in Pr skutterudites with particular attention to (i) mechanism of the crystalline electric field (CEF) splitting leading to a pseudo-quartet ground state; (ii) Kondo effect due to exchange interactions involving the pseudo-quartet; (iii) multipole orders in the lattice of the pseudo-quartet in magnetic field. Competition between the point-charge interaction and hybridization between 4f and conduction electrons is identified as the key for controlling the CEF splitting. It is found that one of two pseudo-spins forming the pseudo-quartet has a ferromagnetic exchange, while the other has an antiferromagnetic exchange with conduction electrons. The Kondo effect is clearly seen in the resistivity calculated by the NCA, provided the low-lying triplet above the singlet is mainly composed of the Γ4-type wave functions. If the weight of the Γ5-type is large in the triplet, the Kondo effect does not appear. This difference caused by the nature of the triplet explains the presence of the Kondo effect in PrFe4P12, and its absence in PrOs4Sb12. By taking the minimal model with antiferro-quadrupole (AFQ) and ferro-type intersite interactions for dipoles and octupoles between nearest-neighbors, the mean-field theory reproduces the overall feature of the multiple ordered phases in PrFe4P12. The AFQ order with the Γ3-type symmetry is found to be stable only as a mixture of O20 and O22 components.

Original languageEnglish
Pages (from-to)134-154
Number of pages21
JournalProgress of Theoretical Physics Supplement
Publication statusPublished - 2005
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)


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