Hybrids of two-dimensional colloidal crystals and gold nanoparticle assemblies for effective surface-enhanced raman scattering with high spatial reproducibility

Miu Danno, Satoshi Yoshinari, Shuto Igari, Jotaro Honda, Takumi Eguchi, Wataru Inoue, Keita Yasuhara, Shuta Hara, Hiroki Ikake, Shigeru Shimizu, Takeshi Toyama, Yasuyuki Kusaka, Nobuko Fukuda, Hirobumi Ushijima, Kouichi Takase, Kosuke Sugawa, Joe Otsuki

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

We have fabricated hybrids of two-dimensional silica colloidal crystals and gold nanospheres for the development of platforms showing effective SERS phenomenon with a high spatial reproducibility. The SERS signal of 4-mercaptobenzoic acid immobilized on the hybrids was enhanced up to 10.4 times by optimizing the silica diameter, as compared with that on the gold nanospheres immobilized on a planar glass plate. We propose that the effective enhancement is induced by hot spots generated at the junction regions between the silica nanospheres.

Original languageEnglish
Pages (from-to)429-432
Number of pages4
JournalChemistry Letters
Volume47
Issue number4
DOIs
Publication statusPublished - 2018
Externally publishedYes

Keywords

  • Gold nanosphere
  • Surface plasmon resonance
  • Surface-enhanced raman scattering

ASJC Scopus subject areas

  • Chemistry(all)

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