Indirect cation-flow method: Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations

Kodai Saito; Koji Ueoka; Kouichi Matsumoto; Seiji Suga; Toshiki Nokami; Jun Ichi Yoshida

doi:10.1002/anie.201100854

Indirect cation-flow method: Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations

Kodai Saito, Koji Ueoka, Kouichi Matsumoto, Seiji Suga, Toshiki Nokami, Jun Ichi Yoshida

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Go with the flow: The indirect cation-flow method based on the generation of highly reactive organic cations from their precursors using electrochemically generated [ArS(ArSSAr)]⁺ was developed in flow microreactor systems (see scheme; Bn=benzyl, M=micromixer, R=microtube reactor). The method was applied to evaluate glycosyl cations such as A or their equivalents and glycosylation reactions.

Original language	English
Pages (from-to)	5153-5156
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	22
DOIs	https://doi.org/10.1002/anie.201100854
Publication status	Published - May 23 2011

Keywords

carbohydrates
cations
electrochemistry
microreactors
sulfur

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201100854

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abstract = "Go with the flow: The indirect cation-flow method based on the generation of highly reactive organic cations from their precursors using electrochemically generated [ArS(ArSSAr)]+ was developed in flow microreactor systems (see scheme; Bn=benzyl, M=micromixer, R=microtube reactor). The method was applied to evaluate glycosyl cations such as A or their equivalents and glycosylation reactions.",

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AU - Saito, Kodai

AU - Ueoka, Koji

AU - Matsumoto, Kouichi

AU - Suga, Seiji

AU - Nokami, Toshiki

AU - Yoshida, Jun Ichi

PY - 2011/5/23

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AB - Go with the flow: The indirect cation-flow method based on the generation of highly reactive organic cations from their precursors using electrochemically generated [ArS(ArSSAr)]+ was developed in flow microreactor systems (see scheme; Bn=benzyl, M=micromixer, R=microtube reactor). The method was applied to evaluate glycosyl cations such as A or their equivalents and glycosylation reactions.

KW - carbohydrates

KW - cations

KW - electrochemistry

KW - microreactors

KW - sulfur

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Indirect cation-flow method: Flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations

Abstract

Keywords

ASJC Scopus subject areas

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