Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

Qiu Jian Rong; Akiyoshi Osaka; Tokuro Nanba; Jun Takada; Yoshinari Miura

doi:10.1007/BF00545458

Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

Qiu Jian Rong, Akiyoshi Osaka, Tokuro Nanba, Jun Takada, Yoshinari Miura

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Abstract

The constitution of glasses in the systems M₂O₃-TeO₂ (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M₂O₃ content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In₂O₃ behaves as a network modifier to yield TeO₃^-units and that discrete BO₃ and BO₄ units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO₄ units of an intermediate configuration, O₃Te^δ+ ...O^δ-.

Original language	English
Pages (from-to)	3793-3798
Number of pages	6
Journal	Journal of Materials Science
Volume	27
Issue number	14
DOIs	https://doi.org/10.1007/BF00545458
Publication status	Published - Jan 1 1992

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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title = "Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides",

abstract = "The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO3-units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.",

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T1 - Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

AU - Rong, Qiu Jian

AU - Osaka, Akiyoshi

AU - Nanba, Tokuro

AU - Takada, Jun

AU - Miura, Yoshinari

PY - 1992/1/1

Y1 - 1992/1/1

N2 - The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO3-units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.

AB - The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO3-units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.

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Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

Abstract

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