Infrared spectra of N2O-hydrogen complexes

Jian Tang; A. R.W. McKellar

doi:10.1063/1.1514207

Infrared spectra of N₂O-hydrogen complexes

Jian Tang, A. R.W. McKellar

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Infrared spectra were recorded and analyzed for weakly bound N₂O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH₂, orthoH₂, orthoD₂, paraD₂, and HD. The observed spectra demonstrated that the j_H=1 forms (N₂O-orthoH₂ and -paraD₂) are significantly more strongly bound than their j_H=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.

Original language	English
Pages (from-to)	8308-8313
Number of pages	6
Journal	Journal of Chemical Physics
Volume	117
Issue number	18
DOIs	https://doi.org/10.1063/1.1514207
Publication status	Published - Nov 8 2002
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1514207

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title = "Infrared spectra of N2O-hydrogen complexes",

abstract = "Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.",

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AU - McKellar, A. R.W.

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AB - Infrared spectra were recorded and analyzed for weakly bound N2O-hydrogen complexes, including all the experimentally accessible forms of molecular hydrogen: paraH2, orthoH2, orthoD2, paraD2, and HD. The observed spectra demonstrated that the jH=1 forms (N2O-orthoH2 and -paraD2) are significantly more strongly bound than their jH=0 counterparts. The spectra were analyzed using a conventional asymmetric rotor Hamiltonian with quadratic centrifugal distortion terms.

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Infrared spectra of N₂O-hydrogen complexes

Abstract

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