Abstract
Infrared spectroscopy was used to analyze OCS-hydrogen van der Waals complexes in the region of vibrational bands. Five distinct species of the complex were observed in a pulsed supersonic jet expansion using a tunable diode laser probe. Results indicated that the band origins were red-shifted relative to the free OCS molecule. The fitted rotational parameters were found to be consistent with the structures having intermolecular separations in the range of 3.6 Å-3.8 Å.
| Original language | English |
|---|---|
| Pages (from-to) | 646-653 |
| Number of pages | 8 |
| Journal | Journal of Chemical Physics |
| Volume | 116 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jan 8 2002 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry