Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

Tomoya Miura; Yuuta Funakoshi; Masahiro Murakami

doi:10.1021/ja412663a

Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

Tomoya Miura, Yuuta Funakoshi, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

199 Citations (Scopus)

Abstract

The rhodium-catalyzed dearomatizing [3 + 2] annulation reaction of 4-(3-arylpropyl)-1,2,3-triazoles is described. It provides a straightforward synthetic pathway from simple 5-aryl-1-alkynes leading to tricyclic 3,4-fused dihydroindoles via the corresponding 1,2,3-triazoles.

Original language	English
Pages (from-to)	2272-2275
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	6
DOIs	https://doi.org/10.1021/ja412663a
Publication status	Published - Feb 12 2014
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja412663a

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abstract = "The rhodium-catalyzed dearomatizing [3 + 2] annulation reaction of 4-(3-arylpropyl)-1,2,3-triazoles is described. It provides a straightforward synthetic pathway from simple 5-aryl-1-alkynes leading to tricyclic 3,4-fused dihydroindoles via the corresponding 1,2,3-triazoles.",

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Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

Abstract

ASJC Scopus subject areas

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