Intramolecular participation in alkoxycarbenium ion pools

Seiji Suga; Shinkiti Suzuki; Jun Ichi Yoshida

doi:10.1021/ol051915r

Intramolecular participation in alkoxycarbenium ion pools

Seiji Suga, Shinkiti Suzuki, Jun Ichi Yoshida

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

(Chemical Equation Presented) Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as "cation pools" by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions.

Original language	English
Pages (from-to)	4717-4720
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	21
DOIs	https://doi.org/10.1021/ol051915r
Publication status	Published - Oct 13 2005
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol051915r

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title = "Intramolecular participation in alkoxycarbenium ion pools",

abstract = "(Chemical Equation Presented) Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as {"}cation pools{"} by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions.",

author = "Seiji Suga and Shinkiti Suzuki and Yoshida, {Jun Ichi}",

year = "2005",

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doi = "10.1021/ol051915r",

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AU - Suzuki, Shinkiti

AU - Yoshida, Jun Ichi

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N2 - (Chemical Equation Presented) Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as "cation pools" by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions.

AB - (Chemical Equation Presented) Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as "cation pools" by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions.

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JO - Organic Letters

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Intramolecular participation in alkoxycarbenium ion pools

Abstract

ASJC Scopus subject areas

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