Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate: Bi2(La,Na)2CuO

Yoshiaki Tanaka; Makoto Nakanishi; Tatsuo Fujii; Jun Takada; Yoshihiro Kusano; Yasunori Ikeda

Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate: Bi₂(La,Na)₂CuO

Yoshiaki Tanaka, Makoto Nakanishi, Tatsuo Fujii, Jun Takada, Yoshihiro Kusano, Yasunori Ikeda

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate, Bi₂(La,Na)₂CuO:, have been investigated. It has been confirmed by powder X-ray diffraction and thermogravimetric analysis that the stage-1 iodine-intercalated compound Bi₂(La,Na)₂CuO ₇l_x with x=1.0 was formed. As in the case of a Bi ₂(Sr,La)₂CuO: (Bi-2201) specimen, expansion of the c-length of the stage-1 iodine-intercalated compound was 3.6 Å, compared with one half that of host compound. After deintercalation of the intercalated iodine, the stage-1 iodine-intercalated compound returned reversibly to the host compound. The powder X-ray diffraction pattern showed the formation of the intermediate phase containing a certain amount of iodine, not assigned to the stage-2 intercalated compound, during the deintercalation. Neither host compound nor iodine-intercalated compound exhibited superconductivity down to 2 K.

Original language	English
Title of host publication	Electroceramic Materials and Applications - Proceedings of the 6th Pacific Rim Conference on Ceramic and Glass Technology
Pages	85-90
Number of pages	6
Publication status	Published - Dec 1 2006
Event	6th Pacific Rim Conference on Ceramic and Glass Technology - Maui, Hawaii, United States Duration: Sept 11 2005 → Sept 16 2005

Publication series

Name	Ceramic Transactions
Volume	196
ISSN (Print)	1042-1122

Other

Other	6th Pacific Rim Conference on Ceramic and Glass Technology
Country/Territory	United States
City	Maui, Hawaii
Period	9/11/05 → 9/16/05

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

Cite this

Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate: Bi₂(La,Na)₂CuO. / Tanaka, Yoshiaki; Nakanishi, Makoto ; Fujii, Tatsuo et al.
Electroceramic Materials and Applications - Proceedings of the 6th Pacific Rim Conference on Ceramic and Glass Technology. 2006. p. 85-90 (Ceramic Transactions; Vol. 196).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Tanaka, Y, Nakanishi, M , Fujii, T, Takada, J, Kusano, Y & Ikeda, Y 2006, Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate: Bi₂(La,Na)₂CuO. in Electroceramic Materials and Applications - Proceedings of the 6th Pacific Rim Conference on Ceramic and Glass Technology. Ceramic Transactions, vol. 196, pp. 85-90, 6th Pacific Rim Conference on Ceramic and Glass Technology, Maui, Hawaii, United States, 9/11/05.

@inproceedings{d05ac5f7872e4851824bd7a4a062be6d,

title = "Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate: Bi2(La,Na)2CuO",

abstract = "Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate, Bi2(La,Na)2CuO:, have been investigated. It has been confirmed by powder X-ray diffraction and thermogravimetric analysis that the stage-1 iodine-intercalated compound Bi2(La,Na)2CuO 7lx with x=1.0 was formed. As in the case of a Bi 2(Sr,La)2CuO: (Bi-2201) specimen, expansion of the c-length of the stage-1 iodine-intercalated compound was 3.6 {\AA}, compared with one half that of host compound. After deintercalation of the intercalated iodine, the stage-1 iodine-intercalated compound returned reversibly to the host compound. The powder X-ray diffraction pattern showed the formation of the intermediate phase containing a certain amount of iodine, not assigned to the stage-2 intercalated compound, during the deintercalation. Neither host compound nor iodine-intercalated compound exhibited superconductivity down to 2 K.",

author = "Yoshiaki Tanaka and Makoto Nakanishi and Tatsuo Fujii and Jun Takada and Yoshihiro Kusano and Yasunori Ikeda",

year = "2006",

month = dec,

day = "1",

language = "English",

isbn = "047008295X",

series = "Ceramic Transactions",

pages = "85--90",

booktitle = "Electroceramic Materials and Applications - Proceedings of the 6th Pacific Rim Conference on Ceramic and Glass Technology",

note = "6th Pacific Rim Conference on Ceramic and Glass Technology ; Conference date: 11-09-2005 Through 16-09-2005",

}

TY - GEN

T1 - Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate

T2 - 6th Pacific Rim Conference on Ceramic and Glass Technology

AU - Tanaka, Yoshiaki

AU - Nakanishi, Makoto

AU - Fujii, Tatsuo

AU - Takada, Jun

AU - Kusano, Yoshihiro

AU - Ikeda, Yasunori

PY - 2006/12/1

Y1 - 2006/12/1

N2 - Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate, Bi2(La,Na)2CuO:, have been investigated. It has been confirmed by powder X-ray diffraction and thermogravimetric analysis that the stage-1 iodine-intercalated compound Bi2(La,Na)2CuO 7lx with x=1.0 was formed. As in the case of a Bi 2(Sr,La)2CuO: (Bi-2201) specimen, expansion of the c-length of the stage-1 iodine-intercalated compound was 3.6 Å, compared with one half that of host compound. After deintercalation of the intercalated iodine, the stage-1 iodine-intercalated compound returned reversibly to the host compound. The powder X-ray diffraction pattern showed the formation of the intermediate phase containing a certain amount of iodine, not assigned to the stage-2 intercalated compound, during the deintercalation. Neither host compound nor iodine-intercalated compound exhibited superconductivity down to 2 K.

AB - Iodine intercalation and deintercalation of a Sr-free Bi-based cuprate, Bi2(La,Na)2CuO:, have been investigated. It has been confirmed by powder X-ray diffraction and thermogravimetric analysis that the stage-1 iodine-intercalated compound Bi2(La,Na)2CuO 7lx with x=1.0 was formed. As in the case of a Bi 2(Sr,La)2CuO: (Bi-2201) specimen, expansion of the c-length of the stage-1 iodine-intercalated compound was 3.6 Å, compared with one half that of host compound. After deintercalation of the intercalated iodine, the stage-1 iodine-intercalated compound returned reversibly to the host compound. The powder X-ray diffraction pattern showed the formation of the intermediate phase containing a certain amount of iodine, not assigned to the stage-2 intercalated compound, during the deintercalation. Neither host compound nor iodine-intercalated compound exhibited superconductivity down to 2 K.

UR - http://www.scopus.com/inward/record.url?scp=33751414087&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33751414087&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33751414087

SN - 047008295X

SN - 9780470082959

T3 - Ceramic Transactions

SP - 85

EP - 90

BT - Electroceramic Materials and Applications - Proceedings of the 6th Pacific Rim Conference on Ceramic and Glass Technology

Y2 - 11 September 2005 through 16 September 2005

ER -