Iridium-catalysed hydrosilylation of cyclopropanes: Via regioselective carbon-carbon bond cleavage

Masahito Murai; Atsushi Nishiyama; Naoki Nishinaka; Haruka Morita; Kazuhiko Takai

doi:10.1039/c7cc04296e

Iridium-catalysed hydrosilylation of cyclopropanes: Via regioselective carbon-carbon bond cleavage

Masahito Murai, Atsushi Nishiyama, Naoki Nishinaka, Haruka Morita, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

While cyclopropanes have been explored as synthetically valuable building blocks, their transformation without conjugated substituents or directly substituted heteroatoms remains challenging. The current study describes the iridium-catalysed ring-opening hydrosilylation of cyclopropanes. A nitrogen-based directing group was found to control the reactivity of iridium active species as well as the regiochemistry of carbon-carbon bond cleavage and hydrosilylation.

Original language	English
Pages (from-to)	9281-9284
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	66
DOIs	https://doi.org/10.1039/c7cc04296e
Publication status	Published - 2017

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "While cyclopropanes have been explored as synthetically valuable building blocks, their transformation without conjugated substituents or directly substituted heteroatoms remains challenging. The current study describes the iridium-catalysed ring-opening hydrosilylation of cyclopropanes. A nitrogen-based directing group was found to control the reactivity of iridium active species as well as the regiochemistry of carbon-carbon bond cleavage and hydrosilylation.",

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T2 - Via regioselective carbon-carbon bond cleavage

AU - Murai, Masahito

AU - Nishiyama, Atsushi

AU - Nishinaka, Naoki

AU - Morita, Haruka

AU - Takai, Kazuhiko

PY - 2017

Y1 - 2017

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AB - While cyclopropanes have been explored as synthetically valuable building blocks, their transformation without conjugated substituents or directly substituted heteroatoms remains challenging. The current study describes the iridium-catalysed ring-opening hydrosilylation of cyclopropanes. A nitrogen-based directing group was found to control the reactivity of iridium active species as well as the regiochemistry of carbon-carbon bond cleavage and hydrosilylation.

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ER -

Iridium-catalysed hydrosilylation of cyclopropanes: Via regioselective carbon-carbon bond cleavage

Abstract

ASJC Scopus subject areas

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