Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst

Seijiro Matsubara; Kazuhiko Takai; Hitosi Nozaki

doi:10.1016/S0040-4039(00)94523-4

Isomerization of primary allylic alcohols to tertiary ones by means of Me₃SiOOSiMe₃-VO(acac)₂ catalyst

Seijiro Matsubara, Kazuhiko Takai, Hitosi Nozaki

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. → sec. have been examined.

Original language	English
Pages (from-to)	3741-3744
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	35
DOIs	https://doi.org/10.1016/S0040-4039(00)94523-4
Publication status	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)94523-4

Cite this

@article{74e7bea3561449f7b58945a6952e85f1,

title = "Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst",

abstract = "The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. → sec. have been examined.",

author = "Seijiro Matsubara and Kazuhiko Takai and Hitosi Nozaki",

year = "1983",

doi = "10.1016/S0040-4039(00)94523-4",

language = "English",

volume = "24",

pages = "3741--3744",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "35",

}

TY - JOUR

T1 - Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst

AU - Matsubara, Seijiro

AU - Takai, Kazuhiko

AU - Nozaki, Hitosi

PY - 1983

Y1 - 1983

N2 - The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. → sec. have been examined.

AB - The title rearrangement proceeds in dichloromethane at 25°C in the presence of the catalyst prepared in situ to give tertiary isomers in good yields. Other rearrangements of sec. → tert. or sec. → sec. have been examined.

UR - http://www.scopus.com/inward/record.url?scp=0003595178&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0003595178&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)94523-4

DO - 10.1016/S0040-4039(00)94523-4

M3 - Article

AN - SCOPUS:0003595178

SN - 0040-4039

VL - 24

SP - 3741

EP - 3744

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 35

ER -

Isomerization of primary allylic alcohols to tertiary ones by means of Me₃SiOOSiMe₃-VO(acac)₂ catalyst

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this