Katsuki-Sharpless asymmetric epoxidation of alkenylethylene glycols: The origin of inverted stereoselection

Takehiko Yoshimitsu; Kunio Ogasawara

doi:10.1039/C39940002197

Katsuki-Sharpless asymmetric epoxidation of alkenylethylene glycols: The origin of inverted stereoselection

Takehiko Yoshimitsu, Kunio Ogasawara

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti ₂(tartrate)₂ complex.

Original language	English
Pages (from-to)	2197-2199
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39940002197
Publication status	Published - Dec 1 1994
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Katsuki-Sharpless asymmetric epoxidation of alkenylethylene glycols: The origin of inverted stereoselection",

abstract = "The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti 2(tartrate)2 complex.",

author = "Takehiko Yoshimitsu and Kunio Ogasawara",

year = "1994",

month = dec,

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doi = "10.1039/C39940002197",

language = "English",

pages = "2197--2199",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T2 - The origin of inverted stereoselection

AU - Yoshimitsu, Takehiko

AU - Ogasawara, Kunio

PY - 1994/12/1

Y1 - 1994/12/1

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AB - The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti 2(tartrate)2 complex.

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JO - Chemical Communications

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ER -

Katsuki-Sharpless asymmetric epoxidation of alkenylethylene glycols: The origin of inverted stereoselection

Abstract

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